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Ch.12 - Solids and Solid-State Materials

Chapter 12, Problem 144a

Small molecules with C=C double bonds, called monomers, can join with one another to form long chain molecules called polymers. Thus, acrylonitrile, H2C=CHCN, polymerizes under appropriate conditions to give polyacrylonitrile, a common starting material for producing the carbon fibers used in composites. (a) Write electron-dot structures for acrylonitrile and polyacrylonitrile, and show how rearranging the electrons can lead to formation of the polymer.

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Well everyone's in this video are being told to draw the electron dot structure for styrene and show the formation of polystyrene via era pushing. So staring. This has a formula of c. H5 which means a benzene ring. Alright so the structure for styrene is that we have the spending ring first. So we have double bonds alternating around the structure. Then we have a branch out one being hydrogen. Then we have sort of this double bond action and we just have two more high regions. So this is the structure for starring and for polystyrene we're having additional polymer. So let's do this in red. So polly starring. So the CC pipe on of the vinyl group goes to C. C. Sigma bond between styrene and another starting molecule. So it's kind of just draw to start. Yeah to styron's. So have the spending bring again with alternating pi bonds. Then we have a branch out with a double bond and then just high genes throughout the structure fulfill fill its octet. Will draw another styrene molecule here. So again Benzine ring alternating double bonds, A branched out double bond and then fulfilling the octet with just hydrogen. So we can see we can put the arrow pushing then in green. So we have the double bond going over to this carbon here and then this little blonde was gone and move further to the other styrene molecules. So drawing partially the product we have these two benzene rings that do not move. We didn't do any sort of air pushing on that end. And then we have this plot in our carbon items down, so we see clearly what's going on. So we have a C. H. We have a CH2, and then I'll just draw the squiggly here, meaning just the rest of the molecule, And then we'll have a central carbon here. Ch two. We have another carbon here, that's just H another squiggly going down here. So this right here again, it's just styron's. We have to draw the electron dot structure for styrene to show the formation of polystyrene here via air pushing which we did in the screen color. So my final answer is just going to be this right over here, going from These two star earrings over to the polystyrene.
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Textbook Question

The mineral wustite is a nonstoichiometric iron oxide with the empirical formula FexO, where x is a number slightly less than 1. Wustite can be regarded as an FeO in which some of the Fe sites are vacant. It has a density of 5.75 g>cm3, a cubic unit cell with an edge length of 431 pm, and a facecentered cubic arrangement of oxygen atoms. (c) Each Fe atom in wustite is in either the +2 or the +3 oxidation state. What percent of the Fe atoms are in the +3 oxidation state?

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Textbook Question

The mineral wustite is a nonstoichiometric iron oxide with the empirical formula FexO, where x is a number slightly less than 1. Wustite can be regarded as an FeO in which some of the Fe sites are vacant. It has a density of 5.75 g>cm3, a cubic unit cell with an edge length of 431 pm, and a facecentered cubic arrangement of oxygen atoms. (d) Using X rays with a wavelength of 70.93 pm, at what angle would third-order diffraction be observed from the planes of atoms that coincide with the faces of the unit cells? Third-order diffraction means that the value of n in the Bragg equation is equal to 3.

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Textbook Question
The alkali metal fulleride superconductors M3C60 have a cubic closest-packed (face-centered cubic) arrangement of nearly spherical C60 3- anions with M+ cations in the holes between the larger C603- ions. The holes are of two types: octahedral holes, which are surrounded octahedrally by six C603- ions; and tetrahedral holes, which are surrounded tetrahedrally by four C603- ions. (c) Specify fractional coordinates for all the octahedral and tetrahedral holes. (Fractional coordinates are fractions of the unit cell edge lengths. For example, a hole at the center of the cell has fractional coordinates 12, 12, 12.)

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Textbook Question

Small molecules with C'C double bonds, called monomers, can join with one another to form long chain molecules called polymers. Thus, acrylonitrile, H2C'CHCN, polymerizes under appropriate conditions to give polyacrylonitrile, a common starting material for producing the carbon fibers used in composites. (b) Use the bond dissociation energies in Table 7.1 to calculate ΔH per H2C'CHCN unit for the conversion of acrylonitrile to polyacrylonitrile. Is the reaction endothermic or exothermic?

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