Chapter 12, Problem 139
Europium(II) oxide is a semiconductor with a band gap of 108 kJ/mol. Below 69 K, it is also ferromagnetic, meaning all the unpaired electrons on europium are aligned in the same direction. How many f electrons are present on each europium ion in EuO? (In lanthanide ions the 4f orbitals are lower in energy than the 6s orbitals.)
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A cube-shaped crystal of an alkali metal, 1.62 mm on an edge, was vaporized in a 500.0 mL evacuated flask. The resulting vapor pressure was 12.5 mm Hg at 802 °C. The structure of the solid metal is known to be body-centered cubic. (b) Use the data in Figure 5.19 to identify the alkali metal.
A cube-shaped crystal of an alkali metal, 1.62 mm on an edge, was vaporized in a 500.0 mL evacuated flask. The resulting vapor pressure was 12.5 mm Hg at 802 °C. The structure of the solid metal is known to be body-centered cubic. (c) What are the densities of the solid and the vapor in g>cm3?
The mineral wustite is a nonstoichiometric iron oxide with the empirical formula FexO, where x is a number slightly less than 1. Wustite can be regarded as an FeO in which some of the Fe sites are vacant. It has a density of 5.75 g>cm3, a cubic unit cell with an edge length of 431 pm, and a facecentered cubic arrangement of oxygen atoms. (c) Each Fe atom in wustite is in either the +2 or the +3 oxidation state. What percent of the Fe atoms are in the +3 oxidation state?
The mineral wustite is a nonstoichiometric iron oxide with the empirical formula FexO, where x is a number slightly less than 1. Wustite can be regarded as an FeO in which some of the Fe sites are vacant. It has a density of 5.75 g>cm3, a cubic unit cell with an edge length of 431 pm, and a facecentered cubic arrangement of oxygen atoms. (d) Using X rays with a wavelength of 70.93 pm, at what angle would third-order diffraction be observed from the planes of atoms that coincide with the faces of the unit cells? Third-order diffraction means that the value of n in the Bragg equation is equal to 3.