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Ch.12 - Solids and Solid-State Materials

Chapter 12, Problem 139

Europium(II) oxide is a semiconductor with a band gap of 108 kJ/mol. Below 69 K, it is also ferromagnetic, meaning all the unpaired electrons on europium are aligned in the same direction. How many f electrons are present on each europium ion in EuO? (In lanthanide ions the 4f orbitals are lower in energy than the 6s orbitals.)

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Hello. Everyone in this video being asked how many electrons are there and then lengthen them three plus ion are being told that the four D orbital is lower in energy than the six S orbital. So lengthen um has an atomic number of 57. So this comes after Xenon and our payroll table like the number of the D block elements. So the electron configuration equation is going to be n S two N -1 DXRN. Here represents the period number and our X here represents the number of electrons in the D orbital. So lengthen them is in the first column of the D block. So our X then is equal to one and the closest noble gas is going to be Xenon in that case the noble gas configuration for lengthen and its neutral state is X E six S two and five D one. Now for lengthen on three plus ion, we removed the electrons in the six S. And the five D sub shell. So the noble gas configuration for this is going to be just our X E. We completely removed R six S two and five D one electrons. So then they fought before diesel shell is completely filled before we reach Arizona in the pr table. So this means to answer the question then, is that there are 10 d electrons in our lengthen um three plus ion. So this right here is going to be my final answer for this question. Thank you all so much for watching
Related Practice
Textbook Question

A cube-shaped crystal of an alkali metal, 1.62 mm on an edge, was vaporized in a 500.0 mL evacuated flask. The resulting vapor pressure was 12.5 mm Hg at 802 °C. The structure of the solid metal is known to be body-centered cubic. (b) Use the data in Figure 5.19 to identify the alkali metal.

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Textbook Question

A cube-shaped crystal of an alkali metal, 1.62 mm on an edge, was vaporized in a 500.0 mL evacuated flask. The resulting vapor pressure was 12.5 mm Hg at 802 °C. The structure of the solid metal is known to be body-centered cubic. (c) What are the densities of the solid and the vapor in g>cm3?

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Textbook Question
Assume that 1.588 g of an alkali metal undergoes complete reaction with the amount of gaseous halogen contained in a 0.500 L flask at 298 K and 755 mm Hg pressure. In the reaction, 22.83 kJ is released 1ΔH = -22.83 kJ2. The product, a binary ionic compound, crystallizes in a unit cell with anions in a face-centered cubic arrangement and with cations centered along each edge between anions. In addition, there is a cation in the center of the cube. (c) Sketch a space-filling, head-on view of the unit cell, labeling the ions. Are the anions in contact with one another?
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Textbook Question

The mineral wustite is a nonstoichiometric iron oxide with the empirical formula FexO, where x is a number slightly less than 1. Wustite can be regarded as an FeO in which some of the Fe sites are vacant. It has a density of 5.75 g>cm3, a cubic unit cell with an edge length of 431 pm, and a facecentered cubic arrangement of oxygen atoms. (c) Each Fe atom in wustite is in either the +2 or the +3 oxidation state. What percent of the Fe atoms are in the +3 oxidation state?

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Textbook Question

The mineral wustite is a nonstoichiometric iron oxide with the empirical formula FexO, where x is a number slightly less than 1. Wustite can be regarded as an FeO in which some of the Fe sites are vacant. It has a density of 5.75 g>cm3, a cubic unit cell with an edge length of 431 pm, and a facecentered cubic arrangement of oxygen atoms. (d) Using X rays with a wavelength of 70.93 pm, at what angle would third-order diffraction be observed from the planes of atoms that coincide with the faces of the unit cells? Third-order diffraction means that the value of n in the Bragg equation is equal to 3.

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Textbook Question
The alkali metal fulleride superconductors M3C60 have a cubic closest-packed (face-centered cubic) arrangement of nearly spherical C60 3- anions with M+ cations in the holes between the larger C603- ions. The holes are of two types: octahedral holes, which are surrounded octahedrally by six C603- ions; and tetrahedral holes, which are surrounded tetrahedrally by four C603- ions. (c) Specify fractional coordinates for all the octahedral and tetrahedral holes. (Fractional coordinates are fractions of the unit cell edge lengths. For example, a hole at the center of the cell has fractional coordinates 12, 12, 12.)

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