Ch.11 - Liquids & Phase Changes
Chapter 11, Problem 93
1,3-Propanediol can form intramolecular as well as intermolecular hydrogen bonds. Draw a structure of 1,3-propanediol showing an intramolecular hydrogen bond.
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Related Practice
Textbook Question
Which substance in each of the following pairs would you
expect to have larger dispersion forces?
(b) HCl or HI
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Textbook Question
Of the substances Xe, CH3Cl, and HF, which has:
(a) The smallest dipole–dipole forces?
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Textbook Question
For each of the following substances, identify the intermolecular
force or forces that predominate. Using your knowledge
of the relative strengths of the various forces, rank the
substances in order of their normal boiling points: Al2O3,
F2, H2O, Br2, ICl, NaCl.
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Textbook Question
Dimethyl ether has the following structure.
(b) Which of the following illustrations depicts the hydrogen
bonding that occurs between dimethyl ether and water?
(i)
(ii)
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Textbook Question
Draw a phase diagram showing how the phase boundaries differ for a pure solvent compared with a solution.
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Textbook Question
Just as individual bonds in a molecule are often polar, molecules
as a whole are also often polar because of the net
sum of individual bond polarities. There are three possible
structures for substances with the formula C2H2Cl2, two of
which are polar overall and one of which is not.
(b) Which of the three structures is nonpolar, and which
two are polar? Explain.
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