Chemical explosions are characterized by the instantaneous release of large quantities of hot gases, which set up a shock wave of enormous pressure (up to 700,000 atm) and velocity (up to 20,000 mi/h). For example, explosion of nitroglycerin (C3H5N3O9) releases four gases, A, B, C, and D: n C3H5N3O9(l) a A(g) + b B(g) + c C(g) + d D(g) Assume that the explosion of 1 mol (227 g) of nitroglycerin releases gases with a temperature of 1950 °C and a volume of 1323 L at 1.00 atm pressure. (e) Write a balanced equation for the explosion of nitroglycerin.
Ch.10 - Gases: Their Properties & Behavior
Chapter 10, Problem 150c
Combustion analysis of 0.1500 g of methyl tert-butyl ether, an octane booster used in gasoline, gave 0.3744 g of CO2 and 0.1838 g of H2O. When a flask having a volume of 1.00 L was evacuated and then filled with methyl tertbutyl ether vapor at a pressure of 100.0 kPa and a temperature of 54.8 °C, the mass of the flask increased by 3.233 g. (c) Write a balanced equation for the combustion reaction.
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Combustion Reactions
Combustion reactions involve the reaction of a substance with oxygen, producing heat and light. Typically, hydrocarbons combust to form carbon dioxide (CO2) and water (H2O). Understanding the stoichiometry of these reactions is crucial for balancing chemical equations, as it allows us to determine the correct ratios of reactants and products.
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Combustion Apparatus
Stoichiometry
Stoichiometry is the calculation of reactants and products in chemical reactions based on the conservation of mass. It involves using balanced chemical equations to relate the amounts of substances consumed and produced. In combustion analysis, stoichiometry helps in determining the empirical formula of the compound being analyzed by relating the masses of CO2 and H2O produced to the original compound.
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Stoichiometry Concept
Molar Mass and Gas Laws
Molar mass is the mass of one mole of a substance, which is essential for converting between grams and moles in chemical calculations. Gas laws, such as the ideal gas law, relate the pressure, volume, temperature, and number of moles of a gas. In this question, understanding these concepts is important for analyzing the vapor of methyl tert-butyl ether and its behavior under specified conditions.
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Related Practice
Textbook Question
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Textbook Question
Combustion analysis of 0.1500 g of methyl tert-butyl ether, an octane booster used in gasoline, gave 0.3744 g of CO2 and 0.1838 g of H2O. When a flask having a volume of 1.00 L was evacuated and then filled with methyl tertbutyl ether vapor at a pressure of 100.0 kPa and a temperature of 54.8 °C, the mass of the flask increased by 3.233 g.
(b) What is the molecular weight and molecular formula of methyl tert-butyl ether?
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Textbook Question
Combustion analysis of 0.1500 g of methyl tert-butyl ether, an octane booster used in gasoline, gave 0.3744 g of CO2 and 0.1838 g of H2O. When a flask having a volume of 1.00 L was evacuated and then filled with methyl tertbutyl ether vapor at a pressure of 100.0 kPa and a temperature of 54.8 °C, the mass of the flask increased by 3.233 g. (a) What is the empirical formula of methyl tert-butyl ether?
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Textbook Question
During a certain time period, 4.0 million tons of SO2 were
released into the atmosphere and subsequently oxidized
to SO3. As explained in the Inquiry, the acid rain produced
when the SO3 dissolves in water can damage marble
statues:
CaCO31s2 + H2SO41aq2S CaSO41aq2 + CO21g2
+ H2O1l2
(b) How many liters of CO2 gas at 20 °C and 735 mm Hg
is produced as a byproduct?.
347
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