Which is the best electron-dot structure for the thiosulfate ion (S2O3 2-) based on the rules of formal charge? (LO 7.16) (a) (b) (c) (d)

Verified step by step guidance

1. Step 1: Determine the total number of valence electrons for the thiosulfate ion (S_2O_3^{2-}). Sulfur has 6 valence electrons, oxygen has 6, and the ion has a 2- charge, so add 2 extra electrons.
2. Step 2: Draw a skeletal structure for the ion. Typically, the less electronegative atom (sulfur) is central, so arrange the atoms as O-S-S-O-O.
3. Step 3: Distribute the valence electrons around the atoms to satisfy the octet rule, starting with the outer atoms (oxygen) and then the central atoms (sulfur).
4. Step 4: Calculate the formal charge for each atom in the structure. The formal charge is calculated as: Formal Charge = (Valence electrons) - (Non-bonding electrons) - 0.5*(Bonding electrons).
5. Step 5: Adjust the structure to minimize formal charges, aiming for the most stable structure where the formal charges are closest to zero, and negative charges are on the more electronegative atoms (oxygen).

Key Concepts

Electron-Dot Structures

Electron-dot structures, or Lewis structures, represent the valence electrons of atoms within a molecule. They illustrate how electrons are shared or transferred between atoms, helping to visualize bonding and lone pairs. Understanding these structures is crucial for predicting molecular geometry and reactivity.

Formal Charge

Formal charge is a theoretical charge assigned to an atom in a molecule, calculated based on the number of valence electrons, the number of non-bonding electrons, and half the number of bonding electrons. It helps determine the most stable electron-dot structure by minimizing the formal charges across the molecule, guiding the selection of the best resonance structure.

Thiosulfate Ion Structure

The thiosulfate ion (S2O3 2-) consists of two sulfur atoms and three oxygen atoms, with a total charge of -2. Its structure involves resonance forms that can be drawn to represent the distribution of electrons. Understanding the specific bonding and electron arrangement in thiosulfate is essential for applying formal charge rules effectively.