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Ch.7 - Covalent Bonding and Electron-Dot Structures
Chapter 7, Problem 59b

Using only the elements Ca, Cl, and Si, give formulas for the following. (b) A molecular compound with polar covalent bonds that obeys the octet rule and has no formal charges

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1
insert step 1: Identify the elements involved in the problem: Calcium (Ca), Chlorine (Cl), and Silicon (Si).
insert step 2: Recognize that a molecular compound typically involves nonmetals, so focus on Cl and Si for forming a molecular compound.
insert step 3: Consider the octet rule, which states that atoms tend to form bonds until they are surrounded by eight electrons.
insert step 4: Determine the possible compound by combining Si and Cl, as Si can form four covalent bonds to satisfy the octet rule.
insert step 5: Write the chemical formula for the compound, ensuring that it has polar covalent bonds and no formal charges.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Polar Covalent Bonds

Polar covalent bonds occur when two atoms share electrons unequally due to differences in electronegativity. In such bonds, the atom with higher electronegativity attracts the shared electrons more strongly, resulting in a partial negative charge on that atom and a partial positive charge on the other. This uneven distribution of charge creates a dipole moment, making the molecule polar.
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Octet Rule

The octet rule is a chemical principle stating that atoms tend to bond in such a way that they each have eight electrons in their valence shell, achieving a stable electron configuration similar to that of noble gases. This rule is particularly relevant for main group elements and guides the formation of covalent bonds, ensuring that atoms share or transfer electrons to fulfill this requirement.
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Formal Charge

Formal charge is a theoretical charge assigned to an atom in a molecule, calculated based on the number of valence electrons, the number of non-bonding electrons, and half the number of bonding electrons. It helps in determining the most stable Lewis structure for a molecule. A stable molecular structure typically has formal charges close to zero, indicating that the distribution of electrons is balanced and that the molecule is energetically favorable.
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