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Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory
Chapter 6, Problem 4

Arrange the ions Rb+, Br-, and Sr2+ from the smallest to the largest. (LO 6.4) (a) Br- < Rb+ < Sr2+ (b) Sr2+ < Br- < Rb+ (c) Rb+ < Sr2+ < Br- (d) Sr2+ < Rb+ < Br-

Verified step by step guidance
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Step 1: Understand that ionic size is influenced by the number of electrons and the effective nuclear charge. Cations (positive ions) are generally smaller than their parent atoms, while anions (negative ions) are larger.
Step 2: Consider the electron configuration of each ion. Rb⁺ has lost one electron compared to its neutral atom, Br⁻ has gained one electron, and Sr²⁺ has lost two electrons.
Step 3: Recognize that losing electrons (as in Rb⁺ and Sr²⁺) results in a smaller ionic radius due to increased effective nuclear charge, while gaining electrons (as in Br⁻) results in a larger ionic radius.
Step 4: Compare the effective nuclear charge and electron configuration: Sr²⁺, having lost two electrons, will be smaller than Rb⁺, which has lost one electron. Br⁻, having gained an electron, will be larger than both.
Step 5: Arrange the ions based on the analysis: Sr²⁺ < Rb⁺ < Br⁻. This corresponds to option (d) in the given choices.
Related Practice
Open Question
What is the ground-state electron configuration for the Mg2+ ion? (LO 6.1) (a) 1s22s22p6 (b) 1s22s22p63s2 (c) 1s22s22p63s23p2 (d) 1s22s22p63s23p6
Textbook Question
Give the ground state electron configuration and number of unpaired electrons in a Ru2+ ion. (LO 6.1, 6.2) (a) 3Kr45s2 4d4 0 unpaired electrons (b) 3Kr45s2 4d6 0 unpaired electrons (c) 3Kr44d6 4 unpaired electrons (d) 3Kr45s24d4 4 unpaired electrons
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Open Question
Identify the false statement about atomic and ionic radii. (LO 6.3) (a) I- has a larger radius than Br- (b) Ba2+ has a smaller radius than Ba (c) Te has a larger radius than Te2- (d) Sr2+ has a smaller radius than Se2-
Textbook Question
Which of the following processes requires the largest input of energy? (LO 6.5) (a) (b) (c) (d)
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Open Question
Phosphorus has a __________ ionization energy than magnesium because __________. (LO 6.5, 6.6) (a) larger; the electron in phosphorus is in a higher n level than the electron in magnesium (b) larger; the electron in phosphorus has a higher Zeff than the electron in magnesium (c) smaller; the electron in phosphorus is in a lower n level than the electron in magnesium (d) smaller; the electron in phosphorus has a lower Zeff than the electron in magnesium
Textbook Question
The successive ionization energies for a second-period element are given. What is the identity of the element? (LO 6.8) Ea1 = 1402 kJ/mol Ea2 = 2856 kJ/mol Ea3 = 4578 kJ/mol Ea4 = 7475 kJ/mol Ea5 = 9445 kJ/mol Ea6 = 53,266 kJ/mol Ea7 = 64,630 kJ/mol (a) Be (b) C (c) N (d) F
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