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Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 131

Microwave ovens work by irradiating food with microwave radiation, which is absorbed and converted into heat. Assum-ing that radiation with l = 15.0 cm is used, that all the energy is converted to heat, and that 4.184 J is needed to raise the temperature of 1.00 g of water by 1.00 °C, how many photons are necessary to raise the temperature of a 350 mL cup of water from 20 °C to 95 °C?

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1. First, we need to calculate the total energy required to raise the temperature of the water. The specific heat capacity of water is given as 4.184 J/g°C. The mass of the water can be calculated from its volume (350 mL) and the density of water (1 g/mL). The temperature change is the final temperature (95°C) minus the initial temperature (20°C). The total energy (Q) can be calculated using the formula Q = mcΔT, where m is the mass, c is the specific heat capacity, and ΔT is the temperature change.
2. Next, we need to calculate the energy of a single photon. The energy (E) of a photon can be calculated using the formula E = hc/λ, where h is Planck's constant (6.626 x 10^-34 J.s), c is the speed of light (3.00 x 10^8 m/s), and λ is the wavelength. The wavelength is given as 15.0 cm, but we need to convert this to meters by multiplying by 0.01.
3. Finally, we can calculate the number of photons required. This is done by dividing the total energy required by the energy of a single photon. This will give us the number of photons necessary to raise the temperature of the water from 20°C to 95°C.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Photon Energy

The energy of a photon is determined by its wavelength, given by the equation E = hc/λ, where E is energy, h is Planck's constant (6.626 x 10^-34 J·s), c is the speed of light (3.00 x 10^8 m/s), and λ is the wavelength in meters. For microwaves with a wavelength of 15.0 cm (0.15 m), this relationship allows us to calculate the energy of each photon, which is essential for determining how many photons are needed to transfer a specific amount of energy to the water.
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Heat Transfer and Specific Heat Capacity

Specific heat capacity is the amount of heat required to raise the temperature of a unit mass of a substance by one degree Celsius. For water, this value is 4.184 J/g·°C. To find the total energy needed to raise the temperature of 350 mL (or 350 g) of water from 20 °C to 95 °C, we use the formula Q = mcΔT, where Q is the heat energy, m is the mass, c is the specific heat capacity, and ΔT is the change in temperature.
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Energy Conservation in Photon Absorption

In the context of microwave heating, energy conservation dictates that the total energy absorbed by the water must equal the energy provided by the photons. This means that the total energy required to heat the water, calculated from the specific heat capacity, must be divided by the energy per photon to find the total number of photons needed. This principle is crucial for understanding how energy is transferred from the microwave radiation to the water.
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Related Practice
Open Question
Draw orbital-filling diagrams for the following atoms. Show each electron as an up or down arrow, and use the abbreviation of the preceding noble gas to represent inner-shell electrons. (a) Sr (b) Cd (c) Atom with Z = 22 (d) Atom with Z = 34
Open Question
The atomic radii of Y (180 pm) and La (187 pm) are significantly different, but the radii of Zr (160 pm) and Hf (159 pm) are essentially identical. Explain.
Textbook Question
One watt (W) is equal to 1 J/s. Assuming that 5.0% of the energy output of a 75 W light bulb is visible light and that the average wavelength of the light is 550 nm, how many photons are emitted by the light bulb each second?
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Textbook Question
The amount of energy necessary to remove an electron from an atom is a quantity called the ionization energy, Ei. This energy can be measured by a technique called photoelectron spectroscopy, in which light of wavelength l is directed at an atom, causing an electron to be ejected. The kinetic energy of the ejected electron (Ek) is measured by determining its veloc-ity, v (Ek = mv2/2), and Ei is then calculated using the conservation of energy principle. That is, the energy of the incident light equals Ei plus Ek. What is the ionization energy of selenium atoms in kilojoules per mole if light with l = 48.2 nm produces electrons with a velocity of 2.371 * 106 m/s? The mass, m, of an electron is 9.109 * 10-31 kg.
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Textbook Question
X rays with a wavelength of 1.54 * 10-10 m are produced when a copper metal target is bombarded with high-energy electrons that have been accelerated by a voltage difference of 30,000 V. The kinetic energy of the electrons equals the product of the voltage difference and the electronic charge in coulombs, where 1 volt-coulomb = 1 J. (a) What is the kinetic energy in joules and the de Broglie wavelength in meters of an electron that has been accel-erated by a voltage difference of 30,000 V?
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Textbook Question
In the Bohr model of atomic structure, electrons are constrained to orbit a nucleus at specific distances, given by the equation

where r is the radius of the orbit, Z is the charge on the nucleus, a0 is the Bohr radius and has a value of 5.292 * 10-11 m, and n is a positive integer (n = 1, 2, 3...) like a principal quantum number. Furthermore, Bohr concluded that the energy level E of an electron in a given orbit is

where e is the charge on an electron. Derive an equation that will let you calculate the difference ∆E between any two energy levels. What relation does your equation have to the Balmer–Rydberg equation?
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