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Ch.5 - Periodicity & Electronic Structure of Atoms
Chapter 5, Problem 103

According to the Aufbau principle, which orbital is filled immediately before each of the following? (a) 3p (b) 4p (c) 4f (d) 5d

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Step 1: Understand the Aufbau principle, which states that electrons fill orbitals starting from the lowest energy level to the highest. This is often represented by the order of filling: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p.
Step 2: For part (a), identify the orbital filled immediately before 3p. According to the order, 3s is filled before 3p.
Step 3: For part (b), identify the orbital filled immediately before 4p. According to the order, 3d is filled before 4p.
Step 4: For part (c), identify the orbital filled immediately before 4f. According to the order, 6s is filled before 4f.
Step 5: For part (d), identify the orbital filled immediately before 5d. According to the order, 4f is filled before 5d.