Skip to main content
Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 137c

Some metals occur naturally in their elemental state while others occur as compounds in ores. Gold, for instance, is found as the free metal; mercury is obtained by heating mercury(II) sulfide ore in oxygen; and zinc is obtained by heating zinc(II) oxide ore with coke (carbon). Judging from their positions in the activity series, which of the metals sil-ver, platinum, and chromium would probably be obtained by (c) heating its oxide with coke?

Verified step by step guidance
1
insert step 1> Identify the metals in question: silver (Ag), platinum (Pt), and chromium (Cr).
insert step 2> Recall the activity series of metals, which ranks metals by their reactivity.
insert step 3> Understand that metals lower in the activity series are less reactive and can be reduced from their oxides by heating with coke (carbon).
insert step 4> Compare the positions of silver, platinum, and chromium in the activity series to determine which is least reactive.
insert step 5> Conclude that the metal that is least reactive and can be reduced by heating its oxide with coke is the one that fits the criteria.

Verified Solution

Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
Was this helpful?

Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Activity Series of Metals

The activity series is a list of metals arranged in order of decreasing reactivity. More reactive metals can displace less reactive metals from their compounds. Understanding where a metal falls in this series helps predict whether it can be extracted from its oxide using a reducing agent like coke.
Recommended video:
Guided course
02:02
Activity Series Chart

Reduction Reactions

Reduction reactions involve the gain of electrons or the removal of oxygen from a substance. In metallurgy, heating an oxide with coke reduces the metal oxide to its elemental form by removing oxygen, allowing the metal to be extracted. This process is crucial for metals that are less reactive.
Recommended video:
Guided course
01:53
Oxidation and Reduction Reactions

Metallurgy and Ore Processing

Metallurgy is the science of extracting metals from their ores and refining them for use. Different methods, such as heating with coke or using other reducing agents, are employed based on the metal's reactivity and the nature of the ore. This knowledge is essential for determining the most efficient extraction method for specific metals.
Recommended video:
Guided course
04:20
Spontaneity of Processes
Related Practice
Textbook Question

A compound with the formula XOCl2 reacts with water, yielding HCl and another acid H2XO3, which has two acidic hydrogens that react with NaOH. When 0.350 g of XOCl2 was added to 50.0 mL of water and the resultant solution was titrated, 96.1 mL of 0.1225 M NaOH was required to react with all the acid. (b) What are the atomic mass and identity of element X?

431
views
Textbook Question
A procedure for determining the amount of iron in a sample is to convert the iron to Fe2+ and then titrate it with a solu-tion of Ce(NH4)2(NO3)6: What is the mass percent of iron in a sample if 1.2284 g of the sample requires 54.91 mL of 0.1018 M Ce(NH4)2(NO3)6 for complete reaction?
649
views
Textbook Question

Some metals occur naturally in their elemental state while others occur as compounds in ores. Gold, for instance, is found as the free metal; mercury is obtained by heating mercury(II) sulfide ore in oxygen; and zinc is obtained by heating zinc(II) oxide ore with coke (carbon). Judging from their positions in the activity series, which of the metals sil-ver, platinum, and chromium would probably be obtained by (a) finding it in its elemental state?

1349
views
Textbook Question
A sample weighing 14.98 g and containing a small amount of copper was treated to give a solution containing aque-ous Cu2+ ions. Sodium iodide was then added to yield solid copper(I) iodide plus I3 with thiosulfate, S2O3 - ion, and the I3 - was titrated 2-. The titration required 10.49 mL of 0.100 M Na2S2O3 for complete reaction. What is the mass percent copper in the sample? The balanced equations are
355
views
Textbook Question

(b) If Ksp = 1.1 * 10-12 for Ag2CrO4, what are the molar concentrations of Ag+ and CrO4 2-in solution?

520
views
Textbook Question
A 100.0 mL solution containing aqueous HCl and HBr was titrated with 0.1235 M NaOH. The volume of base required to neutralize the acid was 47.14 mL. Aqueous AgNO3 was then added to precipitate the Cl-and Br-ions as AgCl and AgBr. The mass of the silver halides obtained was 0.9974 g. What are the molarities of the HCl and HBr in the original solution?
794
views
1
comments