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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 91

How could you use a precipitation reaction to separate each of the following pairs of anions? Write the formula for each reactant you would add, and write a balanced net ionic equation for each reaction. (a)

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Identify a suitable cation that will form an insoluble precipitate with one of the anions but not with the other. This cation will be used as the reactant to add.
Write the formula for the reactant by combining the chosen cation with the anion it will precipitate. Ensure that the charges balance to form a neutral compound.
Mix the solution containing the anions with the solution of the reactant you identified. The cation will react with one of the anions to form an insoluble precipitate.
Write the balanced net ionic equation for the precipitation reaction. This involves only the ions that participate in the formation of the precipitate, omitting the spectator ions.
Filter the mixture to separate the precipitate from the solution. The anion that did not form a precipitate will remain in the solution.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Precipitation Reactions

Precipitation reactions occur when two soluble salts react in solution to form an insoluble solid, known as a precipitate. This process is driven by the formation of a product that is less soluble than the reactants, leading to its separation from the solution. Understanding the solubility rules helps predict which combinations of ions will result in a precipitate.
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Net Ionic Equations

A net ionic equation represents the actual chemical species involved in a reaction, excluding spectator ions that do not participate in the reaction. To write a net ionic equation, one must first write the balanced molecular equation, then identify and remove the ions that remain unchanged on both sides of the equation. This simplification highlights the essential chemical changes occurring during the reaction.
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Anion Separation Techniques

Anion separation techniques involve using selective precipitation to isolate specific anions from a mixture. By adding a reagent that forms a precipitate with one anion while leaving others in solution, chemists can effectively separate and identify different anions. This method is particularly useful in analytical chemistry for qualitative analysis of ionic compounds.
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Related Practice
Textbook Question
Assume that you have an aqueous solution of an unknown salt. Treatment of the solution with dilute BaCl2, AgNO3, and Cu(NO3)2 produces no precipitate. Which of the following anions might the solution contain? (a) Cl- (b) NO3 (c) OH- (d) SO4- 2-
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Textbook Question

How could you use a precipitation reaction to separate each of the following pairs of cations? Write the formula for each reactant you would add, and write a balanced net ionic equation for each reaction. (a)

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Textbook Question

How could you use a precipitation reaction to separate each of the following pairs of cations? Write the formula for each reactant you would add, and write a balanced net ionic equation for each reaction. (b)

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Textbook Question

The following three solutions are mixed: 100.0 mL of 0.100 M Na2SO4, 50.0 mL of 0.300 M ZnCl2, and 100.0 mL of 0.200 M Ba(CN)2. (a) What ionic compounds will precipitate out of solution?

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Textbook Question

The following three solutions are mixed: 100.0 mL of 0.100 M Na2SO4, 50.0 mL of 0.300 M ZnCl2, and 100.0 mL of 0.200 M Ba(CN)2. (b) What is the molarity of each ion remaining in the solution assuming complete precipitation of all insoluble compounds?

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Textbook Question

A 250.0 g sample of a white solid is known to be a mixture of KNO3, BaCl2, and NaCl. When 100.0 g of this mixture is dis-solved in water and allowed to react with excess H2SO4, 67.3 g of a white precipitate is collected. When the remaining 150.0 g of the mixture is dissolved in water and allowed to react with excess AgNO3, 197.6 g of a second precipitate is collected. (a) What are the formulas of the two precipitates?

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