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Ch.3 - Mass Relationships in Chemical Reactions
Chapter 3, Problem 102

Describe the path of a neutral molecule in the mass spectrometer. Why is ionization a necessary first step?

Verified step by step guidance
1
Step 1: Understand the purpose of a mass spectrometer, which is to measure the mass-to-charge ratio of ions. This helps in identifying the composition of a sample by analyzing the ions produced from it.
Step 2: Recognize that a neutral molecule cannot be manipulated by electric or magnetic fields, which are essential components of a mass spectrometer. Therefore, ionization is necessary to convert neutral molecules into charged ions.
Step 3: Describe the ionization process, where a neutral molecule is bombarded with high-energy electrons or photons, resulting in the ejection of one or more electrons and the formation of positively charged ions.
Step 4: Explain that once ionized, the charged ions are accelerated by an electric field and then deflected by a magnetic field. The degree of deflection depends on the mass-to-charge ratio of the ions.
Step 5: Conclude that the path of the ionized molecule in the mass spectrometer is determined by its mass-to-charge ratio, allowing for the separation and detection of different ions, which provides information about the molecular structure and composition of the sample.