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Ch.22 - The Main Group Elements
Chapter 22, Problem 78

Assign charges to the oxygen-containing anions in the following compounds: (a) Na2O (b) K2O2

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1
Identify the oxidation state of the metal in each compound. Sodium (Na) and potassium (K) are both alkali metals, which typically have an oxidation state of +1.
For Na2O, assign the oxidation state of sodium as +1. Since there are two sodium atoms, the total positive charge is 2(+1) = +2.
In Na2O, the compound must be electrically neutral. Therefore, the oxygen must balance the +2 charge from the sodium atoms. Assign the oxidation state of oxygen in Na2O as -2.
For K2O2, assign the oxidation state of potassium as +1. Since there are two potassium atoms, the total positive charge is 2(+1) = +2.
In K2O2, the compound must be electrically neutral. The peroxide ion (O2^2-) has a charge of -2, with each oxygen having an oxidation state of -1.