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Ch.2 - Atoms, Molecules & Ions
Chapter 2, Problem 118

Naturally occurring boron consists of two isotopes: 10^B (19.9%) with an isotopic mass of 10.0129 and 11^B (80.1%) with an isotopic mass of 11.009 31. What is the atomic weight of boron? Check your answer by looking at a periodic table.

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Identify the isotopes of boron and their respective abundances and isotopic masses: 10^B with 19.9% abundance and isotopic mass of 10.0129, and 11^B with 80.1% abundance and isotopic mass of 11.00931.
Convert the percentage abundances into decimal form by dividing by 100: 19.9% becomes 0.199 and 80.1% becomes 0.801.
Calculate the contribution of each isotope to the atomic weight by multiplying the isotopic mass by its decimal abundance: for 10^B, multiply 10.0129 by 0.199; for 11^B, multiply 11.00931 by 0.801.
Add the contributions from each isotope to find the average atomic weight of boron.
Verify the calculated atomic weight by comparing it to the value listed on the periodic table.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Isotopes

Isotopes are variants of a chemical element that have the same number of protons but different numbers of neutrons, resulting in different atomic masses. For example, boron has two stable isotopes, 10^B and 11^B, which differ in their neutron count and thus their mass. Understanding isotopes is crucial for calculating the average atomic weight of an element based on its isotopic composition.
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Atomic Weight Calculation

The atomic weight of an element is calculated as the weighted average of the masses of its isotopes, taking into account their relative abundances. This involves multiplying the mass of each isotope by its percentage abundance (expressed as a fraction) and summing these values. For boron, the calculation would involve the isotopic masses of 10^B and 11^B, weighted by their respective natural abundances.
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Periodic Table

The periodic table is a tabular arrangement of chemical elements, organized by increasing atomic number and grouped by similar properties. It provides essential information, including the atomic weight of elements, which is often a decimal value reflecting the average of all isotopes. Checking the atomic weight of boron on the periodic table can confirm the accuracy of calculations made using isotopic data.
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Related Practice
Open Question
Label the following statements as true or false. (a) The atomic weight and the atomic number of an element have the same numerical value. (b) The molar mass in grams for an element and the atomic weight have the same numerical value.
Open Question
Copper has two naturally occurring isotopes, including 65Cu. Look at the periodic table and tell whether the second isotope is 63Cu or 66Cu.
Textbook Question
A copper wire having a mass of 2.196 g was allowed to react with an excess of sulfur. The excess sulfur was then burned, yielding SO2 gas. The mass of the copper sulfide produced was 2.748 g. (c) Calculate the number of copper ions per cubic centimeter if the density of the copper sulfide is 5.6 g/cm3.
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Textbook Question

Naturally occurring silver consists of two isotopes: 107^Ag (51.84%) with an isotopic mass of 106.9051 and 109^Ag (48.16%) with an isotopic mass of 108.9048. What is the atomic weight of silver? Check your answer in a periodic table.

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Textbook Question

Magnesium has three naturally occurring isotopes: 24Mg (23.985) with 78.99% abundance, 25Mg (24.986) with 10.00% abundance, and a third with 11.01% abundance. Look up the atomic weight of magnesium, and then calculate the mass of the third isotope.

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Textbook Question
A sample of naturally occurring silicon consists of 28^Si (27.9769), 29^Si (28.9765), and 30^Si (29.9738). If the atomic weight of silicon is 28.0855 and the natural abundance of 29^Si is 4.68%, what are the natural abundances of 28^Si and 30^Si?
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