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Ch.14 - Chemical Kinetics
Chapter 14, Problem 121

In Problem 14.113, you wrote a mechanism for the nitric oxide– facilitated decomposition of ozone. Does your mechanism involve a catalyst or a reaction intermediate? Explain.

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Identify the role of a catalyst and a reaction intermediate in a chemical reaction.
Review the mechanism you wrote for the nitric oxide-facilitated decomposition of ozone.
Determine if there is a substance that is consumed in one step and regenerated in a subsequent step, which would indicate a catalyst.
Check if there is a substance that is produced in one step and consumed in a later step, which would indicate a reaction intermediate.
Explain whether the mechanism involves a catalyst, a reaction intermediate, or both, based on your analysis.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Catalysts

A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. It works by providing an alternative reaction pathway with a lower activation energy. In the context of the nitric oxide-facilitated decomposition of ozone, if nitric oxide is regenerated at the end of the reaction, it acts as a catalyst.
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Catalyzed vs. Uncatalyzed Reactions

Reaction Intermediates

A reaction intermediate is a transient species formed during the course of a chemical reaction that is not present in the final products. Intermediates are typically unstable and exist only for a short duration. In the mechanism of ozone decomposition, if a species is formed and consumed in the reaction steps but does not appear in the overall balanced equation, it is classified as an intermediate.
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Reaction Mechanism Example

Reaction Mechanisms

A reaction mechanism is a detailed description of the step-by-step process by which reactants are converted into products. It outlines the sequence of elementary steps, including the formation of intermediates and the role of catalysts. Understanding the mechanism of the nitric oxide-facilitated decomposition of ozone is crucial to determine whether it involves a catalyst or an intermediate.
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Related Practice
Open Question
What distinguishes a catalyst from an intermediate?
Open Question
Sulfur dioxide is oxidized to sulfur trioxide in the following sequence of reactions: 2 SO2(g) + 2 NO2(g) → 2 SO3(g) + 2 NO(g) 2 NO(g) + O2(g) → 2 NO2(g). (b) Identify any molecule that acts as a catalyst or intermediate in this reaction.
Textbook Question
Consider the following mechanism for the decomposition of nitramide 1NH2NO22 in aqueous solution: NH2NO21aq2 + OH-1aq2S NHNO2 -1aq2 + H2O1l2 NHNO2 -1aq2S N2O1g2 + OH-1aq2 (c) How will the rate of the overall reaction be affected if HCl is added to the solution?
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Textbook Question
The rate of the reaction A + B2 S AB + B is directly proportional to the concentration of B2, independent of the concentration of A, and directly proportional to the concentration of a substance C. (c) What is the role of C in this reaction? Why doesn't C appear in the chemical equation for the overall reaction?
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Open Question
The half-life of a typical peptide bond (the C–N bond in a protein backbone) in neutral aqueous solution is about 500 years. When a protease enzyme acts on a peptide bond, the bond’s half-life is about 0.010 s. Assuming that these half-lives correspond to first-order reactions, by what factor does the enzyme increase the rate of the peptide bond breaking reaction?
Textbook Question

Consider the reaction H2(g) + I2(g) → 2 HI(g). The reaction of a fixed amount of H2 and I2 is studied in a cylinder fitted with a movable piston. Indicate the effect of each of the following changes on the rate of the reaction. (a) An increase in temperature at constant volume

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