Open Question
Is the solubility of acetic acid, CH3COOH, greater in water or benzene, C6H6?
Ch.13 - Solutions & Their Properties
Chapter 13, Problem 52
Ethyl alcohol, CH3CH2OH, is miscible with water at 20 °C, but pentyl alcohol, CH3CH2CH2CH2CH2OH, is soluble in water only to the extent of 2.7 g/100 mL. Explain.
Verified step by step guidance1
Step 1: Understand the concept of miscibility and solubility. Miscibility refers to the ability of two liquids to mix in all proportions, forming a homogeneous solution. Solubility, on the other hand, refers to the maximum amount of a substance that can dissolve in a solvent at a given temperature.
Step 2: Analyze the molecular structure of ethyl alcohol (CH3CH2OH) and pentyl alcohol (CH3CH2CH2CH2CH2OH). Both contain a hydroxyl group (-OH) which is polar and can form hydrogen bonds with water, a polar solvent.
Step 3: Consider the impact of the hydrocarbon chain length on solubility. Ethyl alcohol has a shorter hydrocarbon chain (2 carbon atoms) compared to pentyl alcohol (5 carbon atoms). The longer the hydrocarbon chain, the more nonpolar the molecule becomes, reducing its ability to interact with water.
Step 4: Explain the role of hydrogen bonding. Ethyl alcohol can form strong hydrogen bonds with water due to its polar -OH group, making it fully miscible. In contrast, the longer nonpolar chain in pentyl alcohol limits its ability to form hydrogen bonds, reducing its solubility.
Step 5: Conclude by linking molecular structure to solubility behavior. The balance between the polar -OH group and the nonpolar hydrocarbon chain determines the solubility of alcohols in water. Ethyl alcohol's shorter chain allows it to be miscible, while pentyl alcohol's longer chain limits its solubility.
Related Practice
Textbook Question
Predict whether the solubility of butane, C4H10, is greater in water or benzene, C6H6.
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Textbook Question
Arrange the following compounds in order of their expected increasing solubility in water: Br2, KBr, toluene (C7H8, a constituent of gasoline).
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Open Question
Pentyl alcohol, CH3CH2CH2CH2CH2OH, is miscible with octane, C8H18, but methyl alcohol, CH3OH, is insoluble in octane. Explain.
Textbook Question
The dissolution of CaCl2(s) in water is exothermic, with ΔHsoln= - 81.3 kJ>mol. If you were to prepare a 1.00 m solution of CaCl2 beginning with water at 25.0 °C, what would the final temperature of the solution be in °C? Assume that the specific heats of both pure H2O and the solution are the same, 4.18 J>1K g2.
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Textbook Question
Assuming that seawater is an aqueous solution of NaCl, what is its molarity? The density of seawater is 1.025 g/mL at 20 °C, and the NaCl concentration is 3.50 mass %.
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