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Ch.11 - Liquids & Phase Changes
Chapter 11, Problem 35

The dipole moment of methanol is m = 1.70 D. Use arrows to indicate the direction in which electrons are displaced. 3D model of methanol showing molecular structure and dipole moment direction.

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Identify the atoms in the methanol molecule: carbon (C), hydrogen (H), and oxygen (O).
Recognize that the dipole moment is a vector quantity that points from the positive to the negative charge.
Determine the electronegativity of each atom: Oxygen (O) is more electronegative than Carbon (C) and Hydrogen (H).
Draw arrows indicating the direction of electron displacement: from the less electronegative atoms (C and H) towards the more electronegative atom (O).
Ensure the arrows point towards the oxygen atom, indicating the direction of the dipole moment.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Dipole Moment

The dipole moment is a vector quantity that measures the separation of positive and negative charges in a molecule. It is represented in Debye units (D) and indicates the direction of electron displacement due to differences in electronegativity between atoms. A higher dipole moment signifies a greater polarity, influencing the molecule's physical properties and interactions.
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Electronegativity

Electronegativity is the tendency of an atom to attract electrons in a chemical bond. It varies across the periodic table, with elements like fluorine being highly electronegative. In methanol, the oxygen atom is more electronegative than the hydrogen and carbon atoms, leading to an uneven distribution of electron density and the formation of a dipole moment.
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Molecular Geometry

Molecular geometry refers to the three-dimensional arrangement of atoms within a molecule. In methanol (CH3OH), the geometry is influenced by the tetrahedral arrangement around the carbon atom and the bent shape around the oxygen atom due to lone pairs. Understanding molecular geometry is crucial for predicting the dipole moment direction and the overall polarity of the molecule.
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Related Practice
Textbook Question
The following diagram shows a close-up view of part of the vapor-pressure curves for a solvent (red curve) and a solution of the solvent with a second liquid (green curve). Is the second liquid more volatile or less volatile than the solvent?

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Textbook Question
The following phase diagram shows part of the liquid–vapor phase-transition boundaries for two solutions of equal con- centration, one containing a nonvolatile solute and the other containing a volatile solute whose vapor pressure at a given temperature is approximately half that of the pure solvent.

(d) Based on your drawing, what is the approximate normal boiling point of the pure solvent?
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Textbook Question
Choose any two temperatures and corresponding vapor pressures in the table given in Problem 11.30, and use those values to calculate ΔHvap for dichloromethane in kJ/mol. How does the value you calculated compare to the value you read from your plot in Problem 11.32?
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Textbook Question
Dichlorodifluoromethane, CCl2F2, one of the chlorofluo- rocarbon refrigerants responsible for destroying part of the Earth's ozone layer, has Pvap = 40.0 mm Hg at -81.6 °C and Pvap = 400 mm Hg at -43.9 °C. What is the normal boiling point of CCl2F2 in °C?
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Textbook Question
Two dichloroethylene molecules with the same chemical formula 1C2H2Cl22, but different arrangements of atoms are shown.

(c) Which form of dichloroethylene has the highest boiling point?
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Textbook Question
Why is the heat of sublimation, ΔHsubl, equal to the sum of ΔHvap and ΔHfusion at the same temperature?
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