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Ch.9 - Molecular Geometry and Bonding Theories
Chapter 9, Problem 111a

Sulfur tetrafluoride 1SF42 reacts slowly with O2 to form sulfur tetrafluoride monoxide 1OSF42 according to the following unbalanced reaction: SF41g2 + O21g2¡OSF41g2 The O atom and the four F atoms in OSF4 are bonded to a central S atom. (a) Balance the equation.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Balancing Chemical Equations

Balancing chemical equations involves ensuring that the number of atoms of each element is the same on both sides of the equation. This is achieved by adjusting the coefficients in front of the chemical formulas. The law of conservation of mass dictates that matter cannot be created or destroyed in a chemical reaction, thus requiring balanced equations to accurately represent the reaction.
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Molecular Structure and Bonding

Understanding molecular structure and bonding is crucial for predicting how molecules interact during a reaction. In the case of sulfur tetrafluoride monoxide (OSF4), the central sulfur atom is bonded to one oxygen atom and four fluorine atoms, which influences the molecule's reactivity and the overall reaction mechanism. Knowledge of molecular geometry can also aid in visualizing how these atoms are arranged.
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Stoichiometry

Stoichiometry is the quantitative relationship between reactants and products in a chemical reaction. It allows chemists to calculate the amounts of substances consumed and produced, based on the balanced equation. In this context, stoichiometry will help determine the correct coefficients needed to balance the reaction between sulfur tetrafluoride and oxygen, ensuring that the proportions of reactants and products are accurately represented.
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Related Practice
Textbook Question

The energy-level diagram in Figure 9.40 shows that the sideways overlap of a pair of p orbitals produces two molecular orbitals, one bonding and one antibonding. In ethylene there is a pair of electrons in the bonding orbital between the two carbons. Absorption of a photon of the appropriate wavelength can result in promotion of one of the bonding electrons from the to the molecular orbital. a. Assuming this electronic transition corresponds to the HOMO–LUMO transition, what is the HOMO in ethylene?

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Textbook Question

The energy-level diagram in Figure 9.40 shows that the sideways overlap of a pair of p orbitals produces two molecular orbitals, one bonding and one antibonding. In ethylene there is a pair of electrons in the bonding orbital between the two carbons. Absorption of a photon of the appropriate wavelength can result in promotion of one of the bonding electrons from the to the molecular orbital. b. Assuming this electronic transition corresponds to the HOMO–LUMO transition, what is the LUMO in ethylene?

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Textbook Question

The energy-level diagram in Figure 9.40 shows that the sideways overlap of a pair of p orbitals produces two molecular orbitals, one bonding and one antibonding. In ethylene there is a pair of electrons in the bonding orbital between the two carbons. Absorption of a photon of the appropriate wavelength can result in promotion of one of the bonding electrons from the to the molecular orbital. c. Is the bond in ethylene stronger or weaker in the excited state than in the ground state? Why?

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Textbook Question

Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfur tetrafluoride monoxide (OSF4) according to the following unbalanced reaction: SF4(g) + O2(g) → OSF4(g) The O atom and the four F atoms in OSF4 are bonded to a central S atom. (b) Write a Lewis structure of OSF4 in which the formal charges of all atoms are zero.

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Textbook Question

Sulfur tetrafluoride (SF4) reacts slowly with O2 to form sulfur tetrafluoride monoxide (OSF4) according to the following unbalanced reaction: SF4(g) + O2(g) → OSF4(g) The O atom and the four F atoms in OSF4 are bonded to a central S atom. (c) Use average bond enthalpies (Table 8.3) to estimate the enthalpy of the reaction. Is it endothermic or exothermic?

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Textbook Question

Sulfur tetrafluoride 1SF42 reacts slowly with O2 to form sulfur

tetrafluoride monoxide 1OSF42 according to the following

unbalanced reaction:

SF41g2 + O21g2¡OSF41g2

The O atom and the four F atoms in OSF4 are bonded to a

central S atom.

(e) For each of the molecules you drew in part (d), state how many

fluorines are equatorial and how many are axial.

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