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Ch.8 - Basic Concepts of Chemical Bonding

Chapter 8, Problem 95b

The following three Lewis structures can be drawn for N2O:

(b) The N—N bond length in N2O is 1.12 Å, slightly longer than a typical N ≡N bond; and the N— O bond length is 1.19 Å, slightly shorter than a typical N ═O bond (see Table 8.4). Based on these data, which resonance structure best represents N2O?

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Hello everyone today, we are being given the following problem. The possible lewis structures for sulfur cyanide are shown below the bond length for the sulfur carbon bond and the carbon nitrogen bond and sulfur cyanide is 169.167 point nine m and 118.7 kilometers respectively. The carbon nitrogen bond is slightly longer than the typical carbon nitrogen bond and the sulfur carbon bond is slightly shorter than a typical sulfur carbon bond, determine the best resident structure for sulfur cyanide. So in general, a good rule of thumb is that the more shared electrons you have is going to equal a shorter bond. And the opposite is true, meaning the less shared electrons you have, the longer the bond, so you're gonna have a longer bond with the least amount of electrons shared. So if the carbon nitrogen bond here is slightly longer than a typical carbon nitrogen bond, then A and B would contribute. So if our carbon nitrogen bond is longer than the typical. So for nitrogen. So for if the typical sulfur carbon is slightly longer than the typical carbon nitrogen bond, then A and B would contribute to that. However, B and C would contribute if the common carbon nitrogen bond was longer than the carbon sulfur carbon bond. And so in short, we can say that there is no single resident structure that can best represent sulfur cyanide. You have to include them all. And with that we have our answer. I hope this helped until next time
Related Practice
Textbook Question

The triiodide ion, I3-, exists, whereas the corresponding ion with fluorine, F3-, does not. The I3- ion has a linear structure in which two outer I atoms are each bonded to a central I atom. Although I3- is a known ion, F3- is not.

c. Which of the following statements about the existence of I3- versus the nonexistence of F3- is or are true?

i. The Lewis structure of I3- shows 12 electrons around the central I atom.

ii. Elements from the second row of the periodic table generally do not form hypervalent molecules and ions.

iii. An I atom can form a hypervalent molecule or ion more readily than an F atom because of the larger size of the I atom.


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Textbook Question

The hypochlorite ion, ClO-, is the active ingredient in bleach. The perchlorate ion, ClO4-, is a main component of rocket propellants. Draw Lewis structures for both ions. (b) What is the formal charge of Cl in the perchlorate ion, assuming the Cl—O bonds are all single bonds?

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Textbook Question

The following three Lewis structures can be drawn for N2O:

(a) Using formal charges, which of these three resonance forms is likely to be the most important?

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Textbook Question

Mothballs are composed of naphthalene, C10H8, a molecule that consists of two six-membered rings of carbon fused along an edge, as shown in this incomplete Lewis structure:(a) Draw all of the resonance structures of naphthalene. How many are there?

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Textbook Question

Mothballs are composed of naphthalene, C10H8, a molecule that consists of two six-membered rings of carbon fused along an edge, as shown in this incomplete Lewis structure:

(b) Do you expect the C—C bond lengths in the molecule to be similar to those of C—C single bonds, C ═ C double bonds, or intermediate between C—C single and C ═ C double bonds?

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Textbook Question

Mothballs are composed of naphthalene, C10H8, a molecule that consists of two six-membered rings of carbon fused along an edge, as shown in this incomplete Lewis structure:

(c) Not all of the C—C bond lengths in naphthalene are equivalent. Based on your resonance structures, how many C—C bonds in the molecule do you expect to be shorter than the others?

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