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Ch.8 - Basic Concepts of Chemical Bonding

Chapter 8, Problem 90c

A major challenge in implementing the 'hydrogen economy' is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, NaAlH4 can release 5.6% of its mass as H2 upon decomposing to NaH(s), Al(s), and H2(g). NaAlH4 possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (c) Based on electronegativity differences, predict the identity of the polyatomic anion. Draw a Lewis structure for this ion.

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Hi everyone here we have a question telling us that sodium Borough hydride has Covalin bonds that bind poly atomic and ions together. It also has ionic bonds. And we want to make a prediction on the poly atomic and ions identity based on variations of the electro negativity. So we know that polly atomic ions are held together by Covalin bonds. So let's look at some of the possible Covalin bonds for sodium Borough hydride. We have sodium and hydrogen or we have boron and hydrogen. So let's look at our difference in electro negativity. So sodium hydrogen electro negativity ease Equals the absolute value of 0.9 -2.2, which is -1.3. And then we have boron and hydrogen electro negativity ease. And that equals the absolute value of 2 -2.2 Or 2.2, Which equals 0.2. So we want to find the smaller electro negative difference which in this case is four on hydrogen. The smaller electro negative Prince means that it is more Covalin and because it is more Covalin that is more likely that it is the poly atomic ion. So our poly atomic ion is B. H. Four. And that is our final answer. Thank you for watching. Bye.
Related Practice
Textbook Question

(b) Using these partial charges and the atomic radii given in Figure 7.8, estimate the dipole moment of the molecule.

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Textbook Question

(c) The measured dipole moment of BrCl is 0.57 D. If you assume the bond length in BrCl is the sum of the atomic radii, what are the partial charges on the atoms in BrCl using the experimental dipole moment?

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Textbook Question

A major challenge in implementing the 'hydrogen economy' is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, NaAlH4 can release 5.6% of its mass as H2 upon decomposing to NaH(s), Al(s), and H2(g). NaAlH4 possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (b) Which element in NaAlH4 is the most electronegative? Which one is the least electronegative? Which element in NaAlH4 is the least electronegative?

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Textbook Question

A major challenge in implementing the 'hydrogen economy' is finding a safe, lightweight, and compact way of storing hydrogen for use as a fuel. The hydrides of light metals are attractive for hydrogen storage because they can store a high weight percentage of hydrogen in a small volume. For example, NaAlH4 can release 5.6% of its mass as H2 upon decomposing to NaH(s), Al(s), and H2(g). NaAlH4 possesses both covalent bonds, which hold polyatomic anions together, and ionic bonds. (d) What is the formal charge on hydrogen in the polyatomic ion?

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Textbook Question

Structures A, B, and C show the connectivity of the atoms in three different molecules that are isomers of C3H4O. By completing the Lewis structures of these molecules, complete the information in the following table:

Isomer A Isomer B Isomer C

Number of single bonds

Number of double bonds

Number of triple bonds

Number of nonbonding pairs

Textbook Question

The triiodide ion, I3-, exists, whereas the corresponding ion with fluorine, F3-, does not. The I3- ion has a linear structure in which two outer I atoms are each bonded to a central I atom. Although I3- is a known ion, F3- is not.

c. Which of the following statements about the existence of I3- versus the nonexistence of F3- is or are true?

i. The Lewis structure of I3- shows 12 electrons around the central I atom.

ii. Elements from the second row of the periodic table generally do not form hypervalent molecules and ions.

iii. An I atom can form a hypervalent molecule or ion more readily than an F atom because of the larger size of the I atom.


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