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Ch.6 - Electronic Structure of Atoms
Chapter 6, Problem 82b

If you put 120 volts of electricity through a pickle, the pickle will smoke and start glowing orange-yellow. The light is emitted because sodium ions in the pickle become excited; their return to the ground state results in light emission. b. What is the energy of 1.00 mol of these photons? (A mole of photons is called an Einstein.)

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1
Identify the wavelength or frequency of the light emitted by the sodium ions. The orange-yellow light corresponds to a specific wavelength, typically around 589 nm for sodium.
Use the speed of light equation, \( c = \lambda \nu \), to find the frequency (\( \nu \)) if you have the wavelength (\( \lambda \)). Here, \( c \) is the speed of light, approximately \( 3.00 \times 10^8 \) m/s.
Calculate the energy of a single photon using the equation \( E = h \nu \), where \( h \) is Planck's constant, approximately \( 6.626 \times 10^{-34} \) J\cdot s.
Convert the energy of a single photon to the energy of 1 mole of photons (an Einstein) by multiplying the energy of one photon by Avogadro's number, \( 6.022 \times 10^{23} \) mol\(^{-1}\).
Express the final energy in joules per mole, which represents the energy of 1.00 mol of these photons.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Photon Energy

Photon energy is the energy carried by a single photon, which can be calculated using the equation E = hν, where E is energy, h is Planck's constant (6.626 x 10^-34 J·s), and ν (nu) is the frequency of the light. This relationship shows that higher frequency light has more energy, which is relevant when considering the light emitted by excited sodium ions in the pickle.
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Moles and Avogadro's Number

A mole is a unit in chemistry that represents 6.022 x 10^23 entities, known as Avogadro's number. When discussing energy in terms of moles of photons, it is essential to understand that 1 mole of photons contains this fixed number of photons, allowing for the calculation of total energy by multiplying the energy of a single photon by Avogadro's number.
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Excitation and Emission of Electrons

When sodium ions in the pickle are exposed to electricity, their electrons absorb energy and move to a higher energy level, a state known as excitation. When these electrons return to their ground state, they release energy in the form of light. This process is fundamental to understanding how the glowing effect occurs in the pickle when subjected to high voltage.
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Related Practice
Textbook Question

The following electron configurations represent excited states. Identify the element and write its ground-state condensed electron configuration. (b) 3Ar44s13d104p25p1

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Textbook Question

Consider the two waves shown here, which we will consider to represent two electromagnetic radiations: (a) What is the wavelength of wave A?

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Textbook Question

Consider the two waves shown here, which we will consider to represent two electromagnetic radiations: (b) What is the frequency of wave A?

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Textbook Question

Certain elements emit light of a specific wavelength when they are burned or heated in a non-luminous flame. Historically, chemists used such emission wavelengths to determine whether specific elements were present in a sample. Some characteristic wavelengths for a few of the elements are given in the following table:

Ag 328.1 nm Fe 372.0 nm

Au 267.6 nm K 404.7 nm

Ba 455.4 nm Mg 285.2 nm

Ca 422.7 nm Na 589.6 nm

Cu 324.8 nm Ni 341.5 nm

(c) When burned, a sample of an unknown substance is found to emit light of frequency 6.58 * 1014 s-1. Which of these elements is probably in the sample?

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Textbook Question

In August 2011, the Juno spacecraft was launched from Earth with the mission of orbiting Jupiter, arriving nearly five years later in July of 2016. The distance between the two planets varies depending on where each planet is in its orbit, but at the closest, the distance between Jupiter and Earth is 391 million miles. What is the minimum amount of time it takes for a transmitted signal from Juno to reach the Earth?

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Textbook Question

The watt is the derived SI unit of power, the measure of energy per unit time: 1 W=1 J/s. A semiconductor laser in a CD player has an output wavelength of 780 nm and a power level of 0.10 mW. How many photons strike the CD surface during the playing of a CD 69 minutes in length?

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