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Ch.21 - Nuclear Chemistry
Chapter 21, Problem 13b

Write balanced nuclear equations for the following processes:
(b) selenium-72 undergoes electron capture.

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Identify the process: Electron capture involves an inner orbital electron being captured by the nucleus, which combines with a proton to form a neutron.
Write the initial isotope: Selenium-72 is represented as \( ^{72}_{34}\text{Se} \).
Determine the change in the nucleus: During electron capture, a proton is converted into a neutron, so the atomic number decreases by 1, but the mass number remains the same.
Write the resulting isotope: The new element will have an atomic number of 33 (since 34 - 1 = 33), which is arsenic (As), so the resulting isotope is \( ^{72}_{33}\text{As} \).
Write the balanced nuclear equation: \( ^{72}_{34}\text{Se} + e^- \rightarrow ^{72}_{33}\text{As} \), where \( e^- \) represents the captured electron.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Electron Capture

Electron capture is a type of radioactive decay in which an atomic nucleus captures an inner-shell electron, typically from the K-shell. This process results in the conversion of a proton into a neutron, leading to a decrease in the atomic number of the element while the mass number remains unchanged. It is a common decay mode for proton-rich isotopes, allowing them to achieve a more stable configuration.
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Nuclear Equations

Nuclear equations represent the transformation of one element into another during nuclear reactions, including decay processes. They are written to show the initial and final states of the nucleus, including the emission or absorption of particles. In these equations, the atomic number and mass number must be balanced, ensuring that the total number of protons and neutrons remains constant before and after the reaction.
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Selenium-72

Selenium-72 is a radioactive isotope of selenium with 34 protons and 38 neutrons, giving it a mass number of 72. It undergoes various decay processes, including electron capture, to achieve stability. Understanding its nuclear properties and behavior is essential for writing accurate nuclear equations, as it provides the necessary information about the starting material in the reaction.
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