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Ch.20 - Electrochemistry
All textbooksBrown 15th EditionCh.20 - ElectrochemistryProblem 3a
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Chapter 20, Problem 3a

The diagram that follows represents a molecular view of a process occurring at an electrode in a voltaic cell.
Molecular view of a process at an electrode in a voltaic cell, showing electron movement.
(a) Does the process represent oxidation or reduction?
Close-up of molecular interactions at an electrode in a voltaic cell.

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1
Identify the process occurring at the electrode by observing the movement of particles in the diagram.
Note that the particles are moving away from the electrode, indicating a loss of particles from the electrode surface.
Understand that in a voltaic cell, oxidation occurs at the anode where there is a loss of electrons, and reduction occurs at the cathode where there is a gain of electrons.
Recognize that the loss of particles from the electrode suggests that the electrode is losing electrons, which is characteristic of oxidation.
Conclude that the process represented in the diagram is oxidation, as the electrode is losing particles (electrons).

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Textbook Question

In the Brønsted–Lowry concept of acids and bases, acid– base reactions are viewed as proton-transfer reactions. The stronger the acid, the weaker is its conjugate base. If we were to think of redox reactions in a similar way, what particle would be analogous to the proton? Would strong oxidizing agents be analogous to strong acids or strong bases? [Sections 20.1 and 20.2]

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Textbook Question

The diagram that follows represents a molecular view of a process occurring at an electrode in a voltaic cell.


(b) Is the electrode the anode or cathode?

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Textbook Question

The diagram that follows represents a molecular view of a process occurring at an electrode in a voltaic cell.

(c) Why are the atoms in the electrode represented by larger spheres than those in the solution? [Section 20.3]

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Textbook Question

Assume that you want to construct a voltaic cell that uses the following half-reactions: A2+1aq2 + 2 e- ¡ A1s2 Ered ° = -0.10 V B2+1aq2 + 2 e- ¡ B1s2 E°red = -1.10 V You begin with the incomplete cell pictured here in which the electrodes are immersed in water.

(a) What additions must you make to the cell for it to generate a standard emf?

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