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Ch.20 - Electrochemistry
Chapter 20, Problem 30c

Complete and balance the following equations, and identify the oxidizing and reducing agents. (Recall that the O atoms in hydrogen peroxide, H2O2, have an atypical oxidation state.) H2O21aq2 + ClO21aq2 ¡ ClO2-1aq2 + O21g2 (basic solution)

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Oxidation and Reduction

Oxidation and reduction are chemical processes that involve the transfer of electrons between substances. Oxidation refers to the loss of electrons, resulting in an increase in oxidation state, while reduction involves the gain of electrons, leading to a decrease in oxidation state. In redox reactions, one species is oxidized and another is reduced, which is essential for balancing chemical equations.
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Oxidizing and Reducing Agents

An oxidizing agent is a substance that causes oxidation by accepting electrons, while a reducing agent is one that causes reduction by donating electrons. Identifying these agents is crucial in redox reactions, as they play key roles in the electron transfer process. In the given reaction, the oxidizing agent is the species that gets reduced, and the reducing agent is the one that gets oxidized.
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Balancing Redox Reactions in Basic Solution

Balancing redox reactions in a basic solution involves a systematic approach that includes separating the half-reactions, balancing atoms and charges, and then combining them. In basic solutions, hydroxide ions (OH-) are used to balance the hydrogen atoms and neutralize any excess charges. This method ensures that both mass and charge are conserved in the final balanced equation.
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