Chapter 20, Problem 37b
(b) Write the half-reaction that occurs at a hydrogen electrode in acidic aqueous solution when it serves as the anode of a voltaic cell.
Video transcript
A voltaic cell similar to that shown in Figure 20.5 is constructed. One electrode half-cell consists of a silver strip placed in a solution of AgNO3, and the other has an iron strip placed in a solution of FeCl2. The overall cell reaction is Fe1s2 + 2 Ag+1aq2 ¡ Fe2+1aq2 + 2 Ag1s2 (f) In which directions do the cations and anions migrate through the solution?
(a) What is the definition of the volt?
(b) Do all voltaic cells produce a positive cell potential?
(c) Why is it impossible to measure the standard reduction potential of a single half-reaction?
A voltaic cell that uses the reaction PdCl42-1aq2 + Cd1s2 ¡ Pd1s2 + 4 Cl-1aq2 + Cd2+1aq2 has a measured standard cell potential of +1.03 V. (a) Write the two half-cell reactions.
A voltaic cell that uses the reaction PdCl42-1aq2 + Cd1s2 ¡ Pd1s2 + 4 Cl-1aq2 + Cd2+1aq2 has a measured standard cell potential of +1.03 V. (b) By using data from Appendix E, determine E°red for the reaction involving Pd.