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Ch.17 - Additional Aspects of Aqueous Equilibria

Chapter 17, Problem 33d

The accompanying graph shows the titration curves for two monoprotic acids. (d) Estimate the pKa of the weak acid.

Graph showing titration curves of two monoprotic acids labeled A and B.

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Hey everyone, we're given the dehydration curves for two mono product assets and were asked, what is the P K A. For the weak acid first? Let's go ahead and determine which curve is the weak acid. Now, when we look at curve a we can see that we have a lower initial ph and a steeper equivalence point region, which will be this region right here, in comparison to our curve B, which has a less steep equivalence point region and a higher initial ph. And because of these reasons, this means that curve B will be our weak acid. Now infiltrations of a weak acid at the volume halfway to our equivalence point, our ph will equal R p K A. So again, that's at halfway of our equivalence point. So looking at curve B, we can see that our equivalence point is going to be at 40 mL. Now using the knowledge, we just stated, We know that at half of our equivalence point RPH will equal RPKA. So this means at 20 ml RPH will equal RPK. So looking at 20 ml We can see that we're at about a ph of 6.5, Which will also be the value of RPKA. So 6.5 will be our final answer. Now, I hope that made sense. And let us know if you have any questions
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Textbook Question

You have to prepare a pH = 3.50 buffer, and you have the following 0.10 M solutions available: HCOOH, CH3COOH, H3PO4, HCOONa, CH3COONa, and NaH2PO4. Which solutions would you use?

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Textbook Question

You have to prepare a pH = 5.00 buffer, and you have the following 0.10 M solutions available: HCOOH, HCOONa, CH3COOH, CH3COONa, HCN, and NaCN. Which solutions would you use?

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Textbook Question

You have to prepare a pH = 5.00 buffer, and you have the following 0.10 M solutions available: HCOOH, HCOONa, CH3COOH, CH3COONa, HCN, and NaCN. How many milliliters of each solution would you use to make approximately 1 L of the buffer?

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Textbook Question

Compare the titration of a strong, monoprotic acid with a strong base to the titration of a weak, monoprotic acid with a strong base. Assume the strong and weak acid solutions initially have the same concentrations. Indicate whether the following statements are true or false. (a) More base is required to reach the equivalence point for the strong acid than the weak acid.

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Textbook Question

The samples of nitric and acetic acids shown here are both titrated with a 0.100 M solution of NaOH(aq).

Determine whether each of the following statements concerning these titrations is true or false. (a) A larger volume of NaOH1aq2 is needed to reach the equivalence point in the titration of HNO3.

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Textbook Question

Determine whether each of the following statements concerning the titrations in Problem 17.35 is true or false. b. Both titration curves will be essentially the same after passing the equivalence point.