Methanol (CH3OH) can be made by the reaction of CO with H2: CO(π) + 2 H2(π) β CH3OH(π) (a) Use thermochemical data in Appendix C to calculate ΞHΒ° for this reaction.
Ozone, O3, decomposes to molecular oxygen in the stratosphere according to the reaction 2 O3(π) βΆ 3 O2(π). Would increasing the pressure by decreasing the size of the reaction vessel favor the formation of ozone or of oxygen?
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Key Concepts
Le Chatelier's Principle
Stoichiometry of the Reaction
Effect of Pressure on Gas Reactions
Methanol (CH3OH) can be made by the reaction of CO with H2: CO(π) + 2 H2(π) β CH3OH(π) (b) To maximize the equilibrium yield of methanol, would you use a high or low temperature?
Methanol (CH3OH) can be made by the reaction of CO with H2: CO(π) + 2 H2(π) β CH3OH(π) (c) To maximize the equilibrium yield of methanol, would you use a high or low pressure?
(a) Is the dissociation of fluorine molecules into atomic fluorine, F2(π) β 2 ββF(π), an exothermic or endothermic process?
(b) If the temperature is raised by 100 K, does the equilibrium constant for this reaction increase or decrease?
When 2.00 mol of SO2Cl2 is placed in a 2.00-L flask at 303 K, 56% of the SO2Cl2 decomposes to SO2 and Cl2: SO2Cl2(π) β SO2(π) + Cl2(π) (a) Calculate πΎπ for this reaction at this temperature.