Chapter 11, Problem 27b
(b) Which of the following molecules can form hydrogen bonds with other molecules of the same kind: CH3F, CH3NH2, CH3OH, CH3Br?
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Which member in each pair has the greater dispersion forces? (a) H2O or H2S,
Which member in each pair has the greater dispersion forces?(c) SiH4 or GeH4.
Which member in each pair has the stronger intermolecular dispersion forces? (c) CH3CH2CH2Cl or (CH3)2CHCl
Ethylene glycol (HOCH2CH2OH), the major substance in antifreeze, has a normal boiling point of 198 °C. By comparison, ethyl alcohol (CH3CH2OH) boils at 78 °C at atmospheric pressure. Ethylene glycol dimethyl ether (CH3OCH2CH2OCH3) has a normal boiling point of 83 °C, and ethyl methyl ether (CH3CH2OCH3) has a nomral boiling point of 11 °C. (a) Explain why replacement of a hydrogen on the oxygen by a CH3 group generally results in a lower boiling point.
Based on the type or types of intermolecular forces, predict the substance in each pair that has the higher boiling point: (d) phosgene (Cl2CO) or formaldehyde (H2CO)
A number of salts containing the tetrahedral polyatomic anion, BF4-, are ionic liquids, whereas salts containing the somewhat larger tetrahedral ion SO42- do not form ionic liquids. Explain this observation.