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Ch.10 - Gases
Chapter 10, Problem 117d

Gaseous iodine pentafluoride, IF5, can be prepared by the reaction of solid iodine and gaseous fluorine: I21s2 + 5 F21g2¡2 IF51g2 A 5.00-L flask containing 10.0 g of I2 is charged with 10.0 g of F2, and the reaction proceeds until one of the reagents is completely consumed. After the reaction is complete, the temperature in the flask is 125 °C. (d) What is the total mass of reactants and products in the flask?

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Calculate the molar mass of iodine (I2) and fluorine (F2) to determine how many moles of each are present initially. The molar mass of I2 is approximately 253.8 g/mol and for F2 it is about 38.0 g/mol.
Use the stoichiometry of the balanced chemical equation, I2(s) + 5 F2(g) → 2 IF5(g), to determine which reactant is the limiting reactant. This can be done by comparing the mole ratio of I2 to F2 from the initial amounts with the mole ratio required by the balanced equation.
Calculate the amount of IF5 produced by using the limiting reactant's amount and the stoichiometry of the reaction. Since the reaction produces 2 moles of IF5 for every 1 mole of I2 reacted, use this ratio to find the moles of IF5 formed.
Determine the mass of IF5 produced using its molar mass (calculated by adding the molar masses of I and 5 F atoms).
Add the mass of the unreacted excess reactant to the mass of the IF5 produced to find the total mass in the flask after the reaction. The law of conservation of mass states that the total mass before and after the reaction in a closed system must be the same.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Law of Conservation of Mass

The Law of Conservation of Mass states that mass is neither created nor destroyed in a chemical reaction. This principle implies that the total mass of the reactants must equal the total mass of the products. In the context of the given reaction, this means that the combined mass of iodine and fluorine before the reaction will be equal to the mass of iodine pentafluoride produced after the reaction.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on balanced chemical equations. It allows us to determine the amounts of substances consumed and produced in a reaction. In this case, understanding the stoichiometric ratios from the balanced equation for the reaction of iodine and fluorine is essential to identify how much of each reactant is used and how much product is formed.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is crucial for converting between the mass of a substance and the number of moles, which is necessary for stoichiometric calculations. In this problem, calculating the molar masses of iodine (I2) and fluorine (F2) will help determine the initial amounts of reactants in moles, facilitating the analysis of the reaction's outcome.
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Related Practice
Textbook Question

Natural gas is very abundant in many Middle Eastern oil fields. However, the costs of shipping the gas to markets in other parts of the world are high because it is necessary to liquefy the gas, which is mainly methane and has a boiling point at atmospheric pressure of −164°C. One possible strategy is to oxidize the methane to methanol, CH3OH, which has a boiling point of 65°C and can therefore be shipped more readily. Suppose that 10.7×109 ft3 of methane at atmospheric pressure and 25°C is oxidized to methanol. a. What volume of methanol is formed if the density of CH3OH is 0.791 g/mL?

Textbook Question

Gaseous iodine pentafluoride, IF5, can be prepared by the reaction of solid iodine and gaseous fluorine: I21s2 + 5 F21g2¡2 IF51g2 A 5.00-L flask containing 10.0 g of I2 is charged with 10.0 g of F2, and the reaction proceeds until one of the reagents is completely consumed. After the reaction is complete, the temperature in the flask is 125 °C. (a) What is the partial pressure of IF5 in the flask?

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Textbook Question

Gaseous iodine pentafluoride, IF5, can be prepared by the reaction of solid iodine and gaseous fluorine: I21s2 + 5 F21g2¡2 IF51g2 A 5.00-L flask containing 10.0 g of I2 is charged with 10.0 g of F2, and the reaction proceeds until one of the reagents is completely consumed. After the reaction is complete, the temperature in the flask is 125 °C. (c) Draw the Lewis structure of IF5.

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Textbook Question

A 6.53-g sample of a mixture of magnesium carbonate and calcium carbonate is treated with excess hydrochloric acid. The resulting reaction produces 1.72 L of carbon dioxide gas at 28°C and 743 torr pressure. c. Assuming that the reactions are complete, calculate the percentage by mass of magnesium carbonate in the mixture.