Chapter 18, Problem 31b
(b) If a limestone sculp- ture were treated to form a surface layer of calcium sul- fate, would this help to slow down the effects of acid rain? Explain.
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(a) What is the difference between chlorofluorocarbons and hydrofluorocarbons?
(a) When chlorine atoms react with atmospheric ozone, what are the products of the reaction?
(b) Based on average bond enthalpies, would you expect a photon capable of dissociating a C-Cl bond to have sufficient energy to dissociate a C-Br bond?
Alcohol-based fuels for automobiles lead to the production of formaldehyde (CH2O) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photo- chemical smog: CH2O + hn ¡ CHO + H The maximum wavelength of light that can cause this reac- tion is 335 nm. (b) What is the maximum strength of a bond, in kJ>mol, that can be bro- ken by absorption of a photon of 335-nm light?
Alcohol-based fuels for automobiles lead to the production of formaldehyde (CH2O) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photo- chemical smog: CH2O + hn ¡ CHO + H The maximum wavelength of light that can cause this reac- tion is 335 nm. (d) Write out the formaldehyde photodis- sociation reaction, showing Lewis-dot structures.
An important reaction in the formation of photochemical smog is the photodissociation of NO : NO2 + hv → NO(g) + O(g) The maximum wavelength of light that can cause this reac- tion is 420 nm. (a) In what part of the electromagnetic spec- trum is light with this wavelength found?