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Ch.18 - Chemistry of the Environment
Chapter 18, Problem 54

Suppose that tests of a municipal water system reveal the presence of bromate ion, BrO3-. What are the likely origins of this ion?

Verified step by step guidance
1
Step 1: Understand that bromate ion (BrO3-) is a polyatomic ion that can form under certain conditions in water systems.
Step 2: Recognize that bromate can be formed as a byproduct during the disinfection of water, particularly when ozone (O3) is used as a disinfectant.
Step 3: Consider that bromate formation can occur when bromide ions (Br-) present in the water react with ozone during the ozonation process.
Step 4: Note that bromate can also form when chlorine dioxide is used as a disinfectant, although this is less common compared to ozonation.
Step 5: Understand that the presence of bromate in drinking water is a concern due to its potential health effects, and water treatment facilities must monitor and control its levels.
Related Practice
Textbook Question

Magnesium ions are removed in water treatment by the addition of slaked lime, Ca(OH)2. Write a balanced chemical equation to describe what occurs in this process

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Textbook Question

In the lime soda process once used in large scale munici-pal water softening, calcium hydroxide prepared from lime and sodium carbonate are added to precipitate Ca2+ as CaCO3(s) and Mg2+ as Mg(OH)2(s): Ca2+(aq) + CO32-(aq) → CaCO3(s) Mg2+(aq) + 2 OH-(aq) → MgOH2(aq) How many moles of Ca(OH)2 and Na2CO3 should be added to soften (remove the Ca2+ and Mg2+) 1200 L of water in which [Ca2+] = 5.0x10-4 M and [Mg2+] = 7.0x10-4 M?

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Textbook Question

(a) What are trihalomethanes (THMs)? (b) Draw the Lewis structures of two example THMs.

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Open Question
One of the principles of green chemistry is that it is better to use as few steps as possible in making new chemicals. In what ways does following this rule advance the goals of green chemistry? How does this principle relate to energy efficiency?
Open Question
Discuss how catalysts can make processes more energy efficient.
Textbook Question

A reaction for converting ketones to lactones, called the Baeyer–Villiger reaction,

is used in the manufacture of plastics and pharmaceu- ticals. 3-Chloroperbenzoic acid is shock-sensitive, how- ever, and prone to explode. Also, 3-chlorobenzoic acid is a waste product. An alternative process being developed uses hydrogen peroxide and a catalyst consisting of tin deposited within a solid support. The catalyst is readily recovered from the reaction mixture. (a) What would you expect to be the other product of oxidation of the ketone to lactone by hydrogen peroxide?

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