Chapter 9, Problem 83a
Consider the molecular orbitals of the P2 molecule. Assume that the MOs of diatomics from the third row of the periodic table are analogous to those from the second row. (a) Which valence atomic orbitals of P are used to construct the MOs of P2?
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If we assume that the energy-level diagrams for homonuclear diatomic molecules shown in Figure 9.43 can be applied to heteronuclear diatomic molecules and ions, predict the bond order and magnetic behavior of (d) ClF.
Determine the electron configurations for CN+, CN, and CN-. (a) Which species has the strongest C¬N bond?
Determine the electron configurations for CN+, CN, and CN-. (b) Which species, if any, has unpaired electrons?
Consider the molecular orbitals of the P2 molecule. Assume that the MOs of diatomics from the third row of the periodic table are analogous to those from the second row. (c) For the P2 molecule, how many electrons occupy the MO in the figure?
The iodine bromide molecule, IBr, is an interhalogen compound. Assume that the molecular orbitals of IBr are analogous to the homonuclear diatomic molecule F2. (a) Which valence atomic orbitals of I and of Br are used to construct the MOs of IBr?
The iodine bromide molecule, IBr, is an interhalogen compound. Assume that the molecular orbitals of IBr are analogous to the homonuclear diatomic molecule F2. (c) One of the valence MOs of IBr is sketched here. Why are the atomic orbital contributions to this MO different in size?