Chapter 9, Problem 33b
(b) How would you expect the H¬X¬H bond angle to vary in the series H2O, H2S, H2Se? Explain. (Hint: The size of an electron pair domain depends in part on the electronegativity of the central atom.)
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Give the approximate values for the indicated bond angles in the following molecules: (d)
Ammonia, NH3, reacts with incredibly strong bases to produce the amide ion, NH2-. Ammonia can also react with acids to produce the ammonium ion, NH4+. (a) Which species (amide ion, ammonia, or ammonium ion) has the largest H¬N¬H bond angle? (b) Which species has the smallest H¬N¬H bond angle?
(a) Explain why BrF4- is square planar, whereas BF4- is tetrahedral.
(a) Does CS2 have a dipole moment? If so, in which direction does the net dipole point?
(b) It turns out that ozone, O3, has a small dipole moment. How is this possible, given that all the atoms are the same?
(c) Does the molecule BF2Cl have a dipole moment?