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Ch.8 - Basic Concepts of Chemical Bonding
Chapter 8, Problem 110d

Ammonium chloride, NH4Cl, is a very soluble salt in water. (d) How many grams of silver nitrate do you need to add to the solution in part (c) to precipitate all of the chloride as silver chloride?

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1
Step 1: Write down the balanced chemical equation for the reaction. In this case, the reaction is between ammonium chloride (NH4Cl) and silver nitrate (AgNO3) to form silver chloride (AgCl) and ammonium nitrate (NH4NO3). The balanced equation is: NH4Cl + AgNO3 -> AgCl + NH4NO3
Step 2: Determine the stoichiometry of the reaction. From the balanced equation, we can see that one mole of NH4Cl reacts with one mole of AgNO3 to form one mole of AgCl. Therefore, the stoichiometry is 1:1:1.
Step 3: Calculate the number of moles of NH4Cl in the solution from part (c). This can be done by dividing the mass of NH4Cl by its molar mass.
Step 4: Since the stoichiometry of the reaction is 1:1, the number of moles of AgNO3 needed to react with all the NH4Cl is equal to the number of moles of NH4Cl.
Step 5: Calculate the mass of AgNO3 needed by multiplying the number of moles of AgNO3 by its molar mass. This will give you the amount of AgNO3 in grams that you need to add to the solution to precipitate all of the chloride as AgCl.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Solubility and Precipitation

Solubility refers to the ability of a substance to dissolve in a solvent, forming a solution. In this context, ammonium chloride (NH4Cl) is highly soluble in water. When a soluble salt is mixed with another solution containing ions that can form an insoluble compound, a precipitation reaction occurs, resulting in the formation of a solid precipitate.
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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions. It involves using balanced chemical equations to determine the relationships between the amounts of substances involved. In this case, knowing the stoichiometric ratios between ammonium chloride and silver nitrate is essential to calculate how much silver nitrate is needed to completely precipitate the chloride ions as silver chloride (AgCl).
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Molar Mass

Molar mass is the mass of one mole of a substance, expressed in grams per mole (g/mol). It is crucial for converting between the number of moles of a substance and its mass. To find out how many grams of silver nitrate are required to precipitate all the chloride ions, one must first calculate the molar mass of silver nitrate (AgNO3) and use it in conjunction with stoichiometric calculations.
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