Skip to main content
Ch.7 - Periodic Properties of the Elements

Chapter 7, Problem 14

Which of the following statements about effective nuclear charge for the outermost valence electron of an atom is incorrect? (i) The effective nuclear charge can be thought of as the true nuclear charge minus a screening constant due to the other electrons in the atom. (ii) Effective nuclear charge increases going left to right across a row of the periodic table. (iii) Valence electrons screen the nuclear charge more effectively than do core electrons. (iv) The effective nuclear charge shows a sudden decrease when we go from the end of one row to the beginning of the next row of the periodic table. (v) The change in effective nuclear charge going down a column of the periodic table is generally less than that going across a row of the periodic table

Verified Solution
Video duration:
1m
This video solution was recommended by our tutors as helpful for the problem above.
2661
views
Was this helpful?

Video transcript

Hey everyone in this example, we need to identify which of the below statements are false statements. So looking at statement one, it says that the effective nuclear charge is the force exerted by the nucleus onto an electron. And we would actually agree with the statement as a true statement because it correctly defines effective nuclear charge. Moving on to statement B, it says that the core electrons screen the nuclear charge more effectively than valence electrons. We would also recognize that this is a true statement. There's no corrections here needed to be made. So, moving on to statement, see it says that electrons that are further away from the nucleus experience a lower effective nuclear charge. We would also agree with this as a true statement. We can also recall that atoms that have a lower value for their atomic number would therefore have a lower value for their effective nuclear charge. Moving on to statement D, it says that the effective nuclear charge increases from left to right in the periodic table. And this would definitely be a correct recollection of our trend for effective nuclear charge on our periodic table. So, we would agree with this statement. And lastly, we have statement E which says that the change in effective nuclear charge increases down a period in the periodic table. We want to correct this statement here. So that it says decreases down the periodic table. And so this would be a false statement, which means that this is the only correct choice to choose for the false statement given in this example. So this is our final answer. If you have any questions, please leave them down below. Otherwise, I'll see everyone in the next practice video.
Related Practice
Textbook Question

Shown below is a qualitative diagram of the atomic orbital energies for an Na atom. The number of orbitals in each subshell is not shown.

(d) A sodium vapor lamp (Figure 7.23) operates by using electricity to excite the highest-energy electron to the next highest-energy level. Light is produced when the excited electron drops back to the lower level. Which two energy levels are involved in this process for the Na atom?

571
views
Textbook Question

The prefix eka- comes from the Sanskrit word for 'one.' Mendeleev used this prefix to indicate that the unknown element was one place away from the known element that followed the prefix. For example, eka-silicon, which we now call germanium, is one element below silicon. Mendeleev also predicted the existence of eka-manganese, which was not experimentally confirmed until 1937 because this element is radioactive and does not occur in nature. Based on the periodic table shown in Figure 7.1, what do we now call the element Mendeleev called eka-manganese?

2371
views
1
rank
Textbook Question
Among the elements N, O, P, and S, which element or elements have the smallest effect nuclear charge if we use Equation 7.1 to calculate Zeff? Which element or elements have the largest effective nuclear charge?
1048
views
Textbook Question

Detailed calculations show that the value of Zeff for the outermost electrons in Na and K atoms is 2.51+ and 3.49+, respectively. (e) Predict Zeff for the outermost electrons in the Rb atom based on the calculations for Na and K.

1070
views
Textbook Question

Detailed calculations show that the value of Zeff for the outermost electrons in Si and Cl atoms is 4.29+ and 6.12+, respectively. (a) What value do you estimate for Zeff experienced by the outermost electron in both Si and Cl by assuming core electrons contribute 1.00 and valence electrons contribute 0.00 to the screening constant?

4097
views
Textbook Question
Which will experience the greater effect nuclear charge, the electrons in the n = 2 shell in F or the n = 2 shell in B? Which will be closer to the nucleus?
1454
views