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Ch.7 - Periodic Properties of the Elements
Chapter 7, Problem 55

(a) Does metallic character increase, decrease, or remain unchanged as one goes from left to right across a row of the periodic table? (b) Does metallic character increase, decrease, or remain unchanged as one goes down a column of the periodic table?

Verified step by step guidance
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Step 1: Understand the concept of metallic character. Metallic character refers to the tendency of an element to lose electrons and form positive ions (cations). Elements with high metallic character are typically good conductors of electricity and heat, have a shiny appearance, and are malleable and ductile.
Step 2: Analyze the trend across a period (row) in the periodic table. As you move from left to right across a period, elements generally become less metallic. This is because the number of protons in the nucleus increases, which leads to a stronger attraction between the nucleus and the electrons, making it harder for the atoms to lose electrons.
Step 3: Analyze the trend down a group (column) in the periodic table. As you move down a group, the metallic character generally increases. This is because the atomic size increases, and the outer electrons are further from the nucleus, which reduces the effective nuclear charge experienced by these electrons, making it easier for the atoms to lose electrons.
Step 4: Relate these trends to specific examples. For instance, in the second period, lithium (Li) is more metallic than beryllium (Be), and in the alkali metal group, lithium (Li) is less metallic than cesium (Cs).
Step 5: Summarize the trends. Across a period, metallic character decreases from left to right. Down a group, metallic character increases. These trends are due to changes in atomic size and effective nuclear charge.
Related Practice
Open Question
What is the relationship between the ionization energy of an anion with a 1- charge, such as F-, and the electron affinity of the neutral atom, F?
Open Question
Consider the first ionization energy of neon and the electron affinity of fluorine. (b) These two quantities have opposite signs. Which will be positive, and which will be negative? (c) Would you expect the magnitudes of these two quantities to be equal? If not, which one would you expect to be larger?
Textbook Question
Consider the following equation: Al3+1g2 + e-¡Al2+1g2 Which of the following statements are true? (i) The energy change for this process is the second electron affinity of Al atom since Al2+1g2 is formed. (ii) The energy change for this process is the negative of the third ionization energy of the Al atom. (iii) The energy change for this process is the electron affinity of the Al2+ ion.
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Open Question
You read the following statement about two elements X and Y: One of the elements is a good conductor of electricity, and the other is a semiconductor. Experiments show that the first ionization energy of X is twice as great as that of Y. Which element has the greater metallic character?
Open Question
Discussing this chapter, a classmate says, “An element that commonly forms a cation is a metal.” Do you agree or disagree?
Textbook Question

Discussing this chapter, a classmate says, 'Since elements that form cations are metals and elements that form anions are nonmetals, elements that do not form ions are metalloids.' Do you agree or disagree?

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