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Ch.5 - Thermochemistry
Chapter 5, Problem 81

Without doing any calculations, predict the sign of H for each of the following reactions: (a) NaCl1s2¡Na+ 1g2 + Cl-1g2

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Enthalpy Change (ΔH)

Enthalpy change (ΔH) refers to the heat content of a system at constant pressure. It indicates whether a reaction is exothermic (releases heat, ΔH < 0) or endothermic (absorbs heat, ΔH > 0). Understanding ΔH is crucial for predicting the energy changes during chemical reactions, including the dissolution of ionic compounds like NaCl.
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Lattice Energy

Lattice energy is the energy released when gaseous ions combine to form an ionic solid. It is a measure of the strength of the ionic bonds in a crystal lattice. In the case of NaCl, the lattice energy is significant, and its magnitude influences the overall enthalpy change when NaCl dissociates into Na+ and Cl- ions.
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Thermodynamic Favorability

Thermodynamic favorability refers to the likelihood of a reaction occurring based on its energy changes. A reaction is thermodynamically favorable if it results in a decrease in free energy (ΔG < 0). In predicting the sign of ΔH for the dissociation of NaCl, understanding the balance between lattice energy and the energy of the gaseous ions is essential for determining whether the process is favorable.
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