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Ch.5 - Thermochemistry
Chapter 5, Problem 115

A 201-lb man decides to add to his exercise routine by walking up three flights of stairs (45 ft) 20 times per day. Hefigures that theworkrequired to increasehis potential energy in this way will permit him to eat an extra order of French fries, at 245 Cal, without adding to his weight. Is he correct in this assumption?

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Work and Energy

In physics, work is defined as the energy transferred when a force is applied over a distance. The work done against gravity to lift an object is calculated using the formula W = mgh, where W is work, m is mass, g is the acceleration due to gravity, and h is the height. Understanding this concept is crucial for determining the energy expenditure of the man as he walks up the stairs.
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Potential Energy

Potential energy is the energy stored in an object due to its position in a gravitational field. For an object at height h, the potential energy can be expressed as PE = mgh. In this scenario, the man increases his potential energy by ascending the stairs, which can be quantified to assess whether he can offset the caloric intake from the French fries.
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Caloric Energy and Conversion

Calories are a unit of energy commonly used to quantify the energy content of food and the energy expenditure of physical activities. One dietary Calorie (Cal) is equivalent to 1,000 calories (cal). To determine if the man can eat an extra order of French fries without gaining weight, it is essential to compare the energy expended from climbing the stairs to the caloric value of the fries.
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Related Practice
Textbook Question

We can use Hess's law to calculate enthalpy changes that cannot be measured. One such reaction is the conversion of methane to ethane: 2 CH4(g) → C2H6(g) + H2(g) Calculate the ΔH° for this reaction using the following thermochemical data: CH4(g) + 2 O2(g) → CO2(g) + 2 H2O(l) ΔH° = -890.3 kJ 2 H2(g) + O2(g) → 2 H2O(l) H° = -571.6 kJ 2 C2H6(g) + 7 O2(g) → 4 CO2(g) + 6 H2O(l) ΔH° = -3120.8 kJ

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Textbook Question

From the following data for three prospective fuels, calculate which could provide the most energy per unit mass and per unit volume:

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Textbook Question
When magnesium metal is burned in air (Figure 3.6), two products are produced. One is magnesium oxide, MgO. The other is the product of the reaction of Mg with molecular nitrogen, magnesium nitride. When water is added to magnesium nitride, it reacts to form magnesium oxide and ammonia gas. (e) The standard enthalpy of formation of solid magnesium nitride is -461.08 kJ>mol. Calculate the standard enthalpy change for the reaction between magnesium metal and ammonia gas.
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Textbook Question

Sucrose (C12H22O11) is produced by plants as follows: 12 CO2(g) + 11 H2O(l) → C12H22O11 + 12 O2(g) H = 5645 kJ About 4.8 g of sucrose is produced per day per square meter of the earth's surface. The energy for this endothermic reaction is supplied by the sunlight. About 0.1 % of the sunlight that reaches the earth is used to produce sucrose. Calculate the total energy the sun supplies for each square meter of surface area. Give your answer in kilowatts per square meter 1kW/m2 where 1W = 1 J/s2.

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Textbook Question

At 20 °C (approximately room temperature) the average velocity of N2 molecules in air is 1050 mph. (b) What is the kinetic energy (in J) of an N2 molecule moving at this speed?

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Textbook Question

Suppose an Olympic diver who weighs 52.0 kg executes a straight dive from a 10-m platform. At the apex of the dive, the diver is 10.8 m above the surface of the water. (a) What is the potential energy of the diver at the apex of the dive, relative to the surface of the water?

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