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Ch.4 - Reactions in Aqueous Solution

Chapter 4, Problem 96a

The commercial production of nitric acid involves the following chemical reactions:

4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g)

2 NO(g) + O2(g) → 2 NO2(g)

3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g)

(a) Which of these reactions are redox reactions?

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Hey everyone. We're asked to select the redox reaction from the following. Looking at our first one, we can see that we have a base plus an acid. So this means we have an acid base reaction. So A can't be our answer. Looking at B. Let's try and find our oxidation states. So for our sulfur we can see that we had a plus four oxidation state That became plus six And our oxygen went from an oxidation state of zero two negative two. Looking at these values, we can see that sulfur went through oxidation while our oxygen went through reduction. So this means B is going to be our redox reaction. But let's go ahead and look at sea and try to determine what type of reaction this is. Looking at this, we can see that we have a synthesis reaction since we had our to react ints become one product. So I hope that made sense. And let us know if you have any questions.
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Textbook Question

The commercial production of nitric acid involves the following chemical reactions:

4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g)

2 NO(g) + O2(g) → 2 NO2(g)

3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g)

(b) Identify the element undergoing oxidation and the element undergoing reduction. 3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g)

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Textbook Question

The commercial production of nitric acid involves the following chemical reactions:

4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g)

2 NO(g) + O2(g) → 2 NO2(g)

3 NO2(g) + H2O(l) → 2 HNO3(aq) + NO(g)

(c) How many grams of ammonia must you start with to make 1000.0 L of a 0.150 M aqueous solution of nitric acid? Assume all the reactions give 100% yield.

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Textbook Question

Consider the following reagents: zinc, copper, mercury (density 13.6 g/mL), silver nitrate solution, nitric acid solution. (a) Given a 500-mL Erlenmeyer flask and a balloon, can you combine two or more of the foregoing reagents to initiate a chemical reaction that will inflate the balloon? Write a balanced chemical equation to represent this process. What is the identity of the substance that inflates the balloon?

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