Which ions remain in solution, unreacted, after each of the following pairs of solutions is mixed? (c) ammonium phosphate and calcium chloride
Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 28
Separate samples of a solution of an unknown ionic compound are treated with dilute AgNO3, Pb1NO322, and BaCl2. Precipitates form in all three cases. Which of the following could be the anion of the unknown salt: Br-, CO32-, NO3-?
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Key Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Precipitation Reactions
Precipitation reactions occur when two soluble ionic compounds react in solution to form an insoluble solid, known as a precipitate. In this case, the addition of AgNO3, Pb(NO3)2, and BaCl2 to the unknown ionic compound results in precipitates, indicating that the anion in the unknown compound must form insoluble salts with these cations.
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Solubility Rules
Solubility rules are guidelines that help predict whether a compound will dissolve in water. For example, silver (Ag+), lead (Pb2+), and barium (Ba2+) salts have specific solubility characteristics; AgBr and PbBr2 are insoluble, while BaCO3 is also insoluble. Understanding these rules is essential for determining which anions can form precipitates with the given cations.
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Ionic Compounds and Anions
Ionic compounds consist of cations and anions held together by ionic bonds. The identity of the anion is crucial in predicting the behavior of the compound in solution. In this scenario, the possible anions Br-, CO32-, and NO3- must be evaluated based on their ability to form precipitates with the cations present in the reagents used.
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Related Practice
Textbook Question
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Textbook Question
Write balanced net ionic equations for the reactions that occur in each of the following cases. Identify the spectator ion or ions in each reaction. (a) Ba1OH221aq2 + FeCl31aq2¡
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Textbook Question
Write balanced net ionic equations for the reactions that occur in each of the following cases. Identify the spectator ion or ions in each reaction. (c) Na2S1aq2 + CoSO41aq2¡
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Textbook Question
You know that an unlabeled bottle contains an aqueous solution
of one of the following: AgNO3, CaCl2, or Al21SO423. A
friend suggests that you test a portion of the solution with
Ba1NO322 and then with NaCl solutions. According to your
friend's logic, which of these chemical reactions could occur,
thus helping you identify the solution in the bottle?
(a) Barium sulfate could precipitate. (b) Silver chloride
could precipitate. (c) Silver sulfate could precipitate.
(d) More than one, but not all, of the reactions described in
answers a–c could occur. (e) All three reactions described in
answers a–c could occur.
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Textbook Question
Three solutions are mixed together to form a single solution; in the final solution, there are 0.2 mol Pb1CH3COO)2, 0.1 mol Na2S, and 0.1 mol CaCl2 present. What solid(s) will precipitate?
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Textbook Question
State whether each of the following statements is true or false. Justify your answer in each case. (a) Sulfuric acid is a monoprotic acid.
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