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Ch.4 - Reactions in Aqueous Solution
Chapter 4, Problem 22d

Predict whether each of the following compounds is soluble in water: (d) Pb31PO422

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Solubility Rules

Solubility rules are guidelines that help predict whether a compound will dissolve in water. Generally, compounds containing alkali metals (like sodium or potassium) and ammonium ions are soluble. Additionally, nitrates and most sulfates are also soluble, while compounds with lead, barium, and silver often have limited solubility. Understanding these rules is essential for determining the solubility of various ionic compounds.
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Ionic Compounds

Ionic compounds are formed from the electrostatic attraction between positively and negatively charged ions. Their solubility in water depends on the strength of these ionic bonds compared to the interactions with water molecules. When ionic compounds dissolve, they dissociate into their constituent ions, which can then interact with water, affecting their overall solubility. The structure and charge of the ions play a crucial role in this process.
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Lead Compounds

Lead compounds, particularly lead(II) salts, often exhibit low solubility in water. For example, lead(II) phosphate (Pb3(PO4)2) is known to be insoluble due to the strong ionic bonds between lead and phosphate ions. This characteristic is important when predicting the solubility of lead-containing compounds, as they frequently do not dissolve well in aqueous solutions, which can have implications for environmental and health considerations.
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