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Ch.3 - Chemical Reactions and Reaction Stoichiometry
Chapter 3, Problem 82a

Solutions of sulfuric acid and lead(II) acetate react to form solid lead(II) sulfate and a solution of acetic acid. If 5.00 g of sulfuric acid and 5.00 g of lead(II) acetate are mixed, calculate the number of grams of sulfuric acid and grams of acetic acid present in the mixture after the reaction is complete.

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Write the balanced chemical equation for the reaction: \( \text{H}_2\text{SO}_4 + \text{Pb(CH}_3\text{COO)}_2 \rightarrow \text{PbSO}_4 + 2\text{CH}_3\text{COOH} \).
Calculate the molar mass of sulfuric acid (\( \text{H}_2\text{SO}_4 \)) and lead(II) acetate (\( \text{Pb(CH}_3\text{COO)}_2 \)).
Determine the number of moles of sulfuric acid and lead(II) acetate using their respective masses and molar masses.
Identify the limiting reactant by comparing the mole ratio from the balanced equation to the moles calculated.
Calculate the amount of sulfuric acid remaining after the reaction by subtracting the moles of sulfuric acid that reacted (based on the limiting reactant) from the initial moles, and convert this back to grams.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions based on the balanced chemical equation. It allows us to determine the amounts of substances consumed and produced in a reaction, using mole ratios derived from the coefficients of the balanced equation.
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Limiting Reactant

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. Identifying the limiting reactant is crucial for calculating the amounts of reactants left over after the reaction has occurred.
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Molar Mass

Molar mass is the mass of one mole of a substance, typically expressed in grams per mole (g/mol). It is essential for converting between grams and moles, allowing us to quantify the amounts of reactants and products in a chemical reaction based on their respective molar masses.
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Related Practice
Textbook Question

One of the steps in the commercial process for converting ammonia to nitric acid is the conversion of NH3 to NO: 4 NH3(g) + 5 O2(g) → 4 NO(g) + 6 H2O(g) In a certain experiment, 2.00 g of NH3 reacts with 2.50 g of O2. (d) Show that your calculations in parts (b) and (c) are consistent with the law of conservation of mass.

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Textbook Question

Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution of sodium nitrate. A solution containing 3.50 g of sodium carbonate is mixed with one containing 5.00 g of silver nitrate. How many grams of sodium carbonate are present after the reaction is complete? How many grams of sodium nitrate are present after the reaction is complete?

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Textbook Question

Solutions of sodium carbonate and silver nitrate react to form solid silver carbonate and a solution of sodium nitrate. A solution containing 3.50 g of sodium carbonate is mixed with one containing 5.00 g of silver nitrate. How many grams of silver carbonate are present after the reaction is complete?

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Textbook Question

Solutions of sulfuric acid and lead(II) acetate react to form solid lead(II) sulfate and a solution of acetic acid. If 5.00 g of sulfuric acid and 5.00 g of lead(II) acetate are mixed, calculate the number of grams of lead(II) acetate present in the mixture after the reaction is complete.

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Textbook Question

When benzene 1C6H62 reacts with bromine 1Br22, bromobenzene 1C6H5Br2 is obtained: C6H6 + Br2¡C6H5Br + HBr (a) When 30.0 g of benzene reacts with 65.0 g of bromine, what is the theoretical yield of bromobenzene?

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Textbook Question

When benzene 1C6H62 reacts with bromine 1Br22, bromobenzene 1C6H5Br2 is obtained: C6H6 + Br2¡C6H5Br + HBr (b) If the actual yield of bromobenzene is 42.3 g, what is the percentage yield?

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