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Ch.22 - Chemistry of the Nonmetals
Chapter 22, Problem 74

Speculate on why carbon forms carbonate rather than silicate analogs.

Verified step by step guidance
1
Step 1: Understand the basic chemistry of carbon and silicon. Carbon and silicon are both in Group 14 of the periodic table, meaning they have similar valence electron configurations, but they differ significantly in their chemical behavior.
Step 2: Consider the size and electronegativity of carbon versus silicon. Carbon is smaller and more electronegative than silicon, which affects the types of bonds they form. Carbon tends to form strong covalent bonds, while silicon can form more ionic character bonds.
Step 3: Examine the stability of carbonates versus silicates. Carbonates (CO₃²⁻) are stable due to the resonance stabilization of the carbonate ion, where the negative charge is delocalized over the three oxygen atoms. Silicates, on the other hand, form complex structures with silicon-oxygen bonds that are more covalent and less prone to resonance stabilization.
Step 4: Analyze the role of hybridization in carbon compounds. Carbon readily undergoes sp² hybridization to form planar structures like carbonate ions, which is energetically favorable. Silicon, due to its larger size, does not hybridize in the same way and forms tetrahedral structures in silicates.
Step 5: Consider the environmental and biological context. Carbonates are prevalent in biological systems and the Earth's crust due to their solubility and ability to form stable minerals like calcium carbonate. Silicates are more common in geological formations but do not play a significant role in biological systems.