Skip to main content
Ch.22 - Chemistry of the Nonmetals
Chapter 22, Problem 45

Complete the exercises below. Write the Lewis structure for each of the following species, and indicate the structure of each: a. SeO₃²⁻; b. S₂Cl₂; c. chlorosulfonic acid, HSO₃Cl (chlorine is bonded to sulfur).

Verified step by step guidance
1
Step 1: Determine the total number of valence electrons for each species. For SeO₃²⁻, calculate the valence electrons from Se and O, and add 2 for the charge. For S₂Cl₂, sum the valence electrons from S and Cl. For HSO₃Cl, sum the valence electrons from H, S, O, and Cl.
Step 2: Draw the skeletal structure for each species. For SeO₃²⁻, place Se in the center with O atoms around it. For S₂Cl₂, place the S atoms in the center with Cl atoms bonded to them. For HSO₃Cl, place S in the center with O, Cl, and H atoms bonded to it, ensuring Cl is bonded to S.
Step 3: Distribute the valence electrons around the atoms to satisfy the octet rule, starting with the outer atoms. For SeO₃²⁻, distribute electrons to the O atoms first. For S₂Cl₂, distribute electrons to the Cl atoms. For HSO₃Cl, distribute electrons to the O and Cl atoms.
Step 4: Check for formal charges and adjust the structure if necessary to minimize them. For SeO₃²⁻, consider forming double bonds between Se and O to reduce formal charges. For S₂Cl₂, ensure the formal charges are minimized. For HSO₃Cl, adjust bonds to minimize formal charges, especially around S.
Step 5: Verify that all atoms have complete octets (or duets for hydrogen) and that the total number of electrons used matches the total number of valence electrons calculated in Step 1.
Related Practice
Open Question
Complete the exercises below. Write the chemical formula for each of the following compounds, and indicate the oxidation state of the group 6A element in each: a. sulfur tetrachloride, b. selenium trioxide, c. sodium thiosulfate, d. hydrogen sulfide, e. sulfuric acid, f. sulfur dioxide, g. mercury telluride.
Open Question
Complete the exercises below. In aqueous solution, hydrogen sulfide reduces dilute HNO₃ to NO₂. In all cases, under appropriate conditions, the product is elemental sulfur. Write a balanced net ionic equation for each reaction.
Open Question
Complete the exercises below. An aqueous solution of SO₂ reduces a. aqueous KMnO₄ to MnSO₄ (aq) b. acidic aqueous K₂Cr₂O₇ to aqueous Cr⁵⁺, c. aqueous Hg₂(NO₃)₂ to mercury metal. Write balanced equations for these reactions.
Open Question
Complete the exercises below. The SF₅⁻ ion is formed when SF₄ (g) reacts with fluoride salts containing large cations, such as CsF(s). Draw the Lewis structures for SF₄ and SF₅⁻, and predict the molecular structure of each.
Open Question
Complete the exercises below. Write a balanced equation for each of the following reactions: a. Sulfur dioxide reacts with water. b. Solid zinc sulfide reacts with hydrochloric acid. c. Elemental sulfur reacts with sulfite ion to form thiosulfate. d. Sulfur trioxide is dissolved in sulfuric acid.
Open Question
Complete the exercises below. Write a balanced equation for each of the following reactions. a. Hydrogen selenide can be prepared by the reaction of an aqueous acid solution on aluminum selenide. b. Sodium thiosulfate is used to remove excess Cl₂ from chlorine-bleached fabrics. The thiosulfate ion forms SO₄²⁻ and elemental sulfur, while Cl₂ is reduced to Cl⁻.