Chapter 20, Problem 3a
The diagram that follows represents a molecular view of a process occurring at an electrode in a voltaic cell.
(a) Does the process represent oxidation or reduction?
Video transcript
In the Brønsted–Lowry concept of acids and bases, acid– base reactions are viewed as proton-transfer reactions. The stronger the acid, the weaker is its conjugate base. If we were to think of redox reactions in a similar way, what particle would be analogous to the proton? Would strong oxidizing agents be analogous to strong acids or strong bases? [Sections 20.1 and 20.2]
The diagram that follows represents a molecular view of a process occurring at an electrode in a voltaic cell.
(b) Is the electrode the anode or cathode?
The diagram that follows represents a molecular view of a process occurring at an electrode in a voltaic cell.
(c) Why are the atoms in the electrode represented by larger spheres than those in the solution? [Section 20.3]
Assume that you want to construct a voltaic cell that uses the following half-reactions: A2+1aq2 + 2 e- ¡ A1s2 Ered ° = -0.10 V B2+1aq2 + 2 e- ¡ B1s2 E°red = -1.10 V You begin with the incomplete cell pictured here in which the electrodes are immersed in water.
(a) What additions must you make to the cell for it to generate a standard emf?