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Ch.20 - Electrochemistry
Chapter 20, Problem 28c

Indicate whether each statement is true or false: (c) A salt bridge or permeable barrier is necessary to allow a voltaic cell to operate.

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Understand the function of a voltaic cell: A voltaic cell, also known as a galvanic cell, is an electrochemical cell that uses a chemical reaction to produce electrical energy.
Identify the role of a salt bridge: A salt bridge or permeable barrier is used to maintain electrical neutrality within the internal circuit, preventing the solutions in the two half-cells from mixing directly.
Consider the consequences of not having a salt bridge: Without a salt bridge, the flow of electrons would stop as the solutions in the half-cells would quickly become charged, disrupting the flow of electricity.
Evaluate the necessity of the salt bridge: Since the salt bridge is crucial for maintaining charge balance and allowing the continuous flow of electrons, it is necessary for the operation of a voltaic cell.
Conclude the statement: Based on the understanding that a salt bridge is essential for the operation of a voltaic cell, determine whether the statement is true or false.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Voltaic Cell

A voltaic cell, also known as a galvanic cell, is an electrochemical cell that converts chemical energy into electrical energy through spontaneous redox reactions. It consists of two half-cells, each containing an electrode and an electrolyte, which are connected by a conductive path. The flow of electrons from the anode to the cathode generates an electric current.
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Salt Bridge

A salt bridge is a device used in voltaic cells to maintain electrical neutrality by allowing the flow of ions between the two half-cells. It typically contains a gel or solution of an inert electrolyte, which prevents the mixing of the two different solutions while enabling ion migration. This is crucial for completing the circuit and sustaining the flow of electrons.
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Electrochemical Reactions

Electrochemical reactions involve the transfer of electrons between chemical species, leading to oxidation and reduction processes. In a voltaic cell, oxidation occurs at the anode, where electrons are released, while reduction occurs at the cathode, where electrons are accepted. The movement of electrons through an external circuit and ions through the salt bridge is essential for the cell's operation.
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