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Ch.2 - Atoms, Molecules, and Ions
Chapter 2, Problem 96

Copper (Cu) consists of two naturally occurring isotopes with masses of 62.9296 and 64.9278 u. (a) How many protons and neutrons are in the nucleus of each isotope? Write the complete atomic symbol for each, showing the atomic number and mass number. (b) The average atomic mass of Cu is 63.55 u. Calculate the abundance of each isotope.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Isotopes

Isotopes are variants of a chemical element that have the same number of protons but different numbers of neutrons, resulting in different mass numbers. For example, copper has two isotopes: one with 29 protons and 34 neutrons (mass number 63) and another with 29 protons and 36 neutrons (mass number 65). Understanding isotopes is crucial for determining the composition and properties of elements.
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Atomic Symbol

The atomic symbol of an element is a notation that represents the element's identity, including its atomic number (number of protons) and mass number (total number of protons and neutrons). For copper, the complete atomic symbols for its isotopes are written as 63Cu and 65Cu, where the superscript indicates the mass number. This notation is essential for distinguishing between different isotopes in chemical equations and calculations.
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Average Atomic Mass and Abundance

The average atomic mass of an element is a weighted average of the masses of its isotopes, taking into account their relative abundances. To calculate the abundance of each isotope, one can set up equations based on the average atomic mass and the known masses of the isotopes. This concept is vital for understanding how isotopes contribute to the overall mass of an element as found on the periodic table.
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Related Practice
Textbook Question

The nucleus of 6Li is a powerful absorber of neutrons. It exists in the naturally occurring metal to the extent of 7.5%. In the era of nuclear deterrence, large quantities of lithium were processed to remove 6Li for use in hydrogen bomb production. The lithium metal remaining after removal of 6Li was sold on the market. (b) The atomic masses of 6Li and 7Li are 6.015122 and 7.016004 u, respectively. A sample of lithium depleted in the lighter isotope was found on analysis to contain 1.442% 6Li. What is the average atomic weight of this sample of the metal?

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Textbook Question

The element argon has three naturally occurring isotopes, with 18, 20, and 22 neutrons in the nucleus, respectively. (a) Write the full chemical symbols for these three isotopes.

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Textbook Question

The element chromium (Cr) consists of four naturally occurring isotopes with atomic masses 49.9460, 51.9405, 52.9407, and 53.9389 u. The relative abundances of these four isotopes are 4.3, 83.8, 9.5, and 2.4%, respectively. From these data, calculate the atomic weight of chromium.

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Textbook Question

There are two different isotopes of bromine atoms. Under normal conditions, elemental bromine consists of Br2 molecules, and the mass of a Br2 molecule is the sum of the masses of the two atoms in the molecule. The mass spectrum of Br2 consists of three peaks: Mass (u) Relative Size 157.836 0.2569 159.834 0.4999 161.832 0.2431 (b) What is the mass of each isotope?

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Textbook Question

There are two different isotopes of bromine atoms. Under normal conditions, elemental bromine consists of Br2 molecules, and the mass of a Br2 molecule is the sum of the masses of the two atoms in the molecule. The mass spectrum of Br2 consists of three peaks: Mass (u) Relative Size 157.836 0.2569 159.834 0.4999 161.832 0.2431 (c) Determine the average molecular mass of a Br2 molecule.

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Textbook Question

There are two different isotopes of bromine atoms. Under normal conditions, elemental bromine consists of Br2 molecules, and the mass of a Br2 molecule is the sum of the masses of the two atoms in the molecule. The mass spectrum of Br2 consists of three peaks: Mass (u) Relative Size 157.836 0.2569 159.834 0.4999 161.832 0.2431 (d) Determine the average atomic mass of a bromine atom

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