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Ch.2 - Atoms, Molecules, and Ions
Chapter 2, Problem 38b

Consider the mass spectrometer shown in Figure 2.11. Determine whether each of the following statements is true or false. If false, correct the statement to make it true: (b) The height of each peak in the mass spectrum is inversely proportional to the mass of that isotope.

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Key Concepts

Here are the essential concepts you must grasp in order to answer the question correctly.

Mass Spectrometry

Mass spectrometry is an analytical technique used to measure the mass-to-charge ratio of ions. It involves ionizing chemical species and sorting the ions based on their mass. The resulting mass spectrum provides information about the composition and abundance of different isotopes in a sample.
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Isotope Abundance

Isotope abundance refers to the relative amount of each isotope of an element present in a sample. In mass spectrometry, the height of each peak in the mass spectrum corresponds to the abundance of the respective isotope, with taller peaks indicating higher abundance, not inversely proportional to mass.
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Mass Spectrum Interpretation

Interpreting a mass spectrum involves analyzing the peaks to determine the identity and relative abundance of isotopes. The position of each peak indicates the mass of the isotope, while the height reflects its abundance. Therefore, the statement in the question is false; peak height is directly proportional to isotope abundance, not inversely related to mass.
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Guided course
02:53
Electromagnetic Spectrum
Related Practice
Textbook Question

Only two isotopes of copper occur naturally: 63Cu (atomic mass = 62.9296 amu; abundance 69.17%) 65Cu (atomic mass = 64.9278 amu; abundance 30.83%). Calculate the atomic weight (average atomic mass) of copper.

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Textbook Question

(a) Thomson's cathode-ray tube (Figure 2.4) and the mass spectrometer (Figure 2.11) both involve the use of electric or magnetic fields to deflect charged particles. What are the charged particles involved in each of these experiments?

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Textbook Question

Consider the mass spectrometer shown in Figure 2.11. Determine whether each of the following statements is true or false. If false, correct the statement to make it true: (a) The paths of neutral (uncharged) atoms are not affected by the magnet.

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Textbook Question

Massspectrometry is more often applied to molecules than to atoms. We will see in Chapter 3 that the molecular weight of a molecule is the sum of the atomic weights of the atoms in the molecule. The mass spectrum of H2 is taken under conditions that prevent decomposition into H atoms. The two naturally occurring isotopes of hydrogen are 1H (atomic mass = 1.00783 amu; abundance 99.9885%) and 2H (atomic mass = 2.01410; abundance 0.0115%). (a) How many peaks will the mass spectrum have?

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Textbook Question

Massspectrometry is more often applied to molecules than to atoms. We will see in Chapter 3 that the molecular weight of a molecule is the sum of the atomic weights of the atoms in the molecule. The mass spectrum of H2 is taken under conditions that prevent decomposition into H atoms. The two naturally occurring isotopes of hydrogen are 1H (atomic mass = 1.00783 amu; abundance 99.9885%) and 2H (atomic mass = 2.01410; abundance 0.0115%). (c) Which peak will be the largest, and which the smallest?

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Textbook Question

For each of the following elements, write its chemical symbol, locate it in the periodic table, give its atomic number, and indicate whether it is a metal, metalloid, or nonmetal: (g) arsenic.

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