Chapter 19, Problem 31b
Would each of the following changes increase, decrease, or have no effect on the number of microstates available to a system: (b) decrease in volume
Video transcript
(a) What is the difference between a state and a microstate of a system?
(b) As a system goes from state A to state B, its entropy decreases. What can you say about the number of microstates corresponding to each state?
(c) In a particular spontaneous process, the number of microstates available to the system decreases. What can you conclude about the sign of ΔSsurr?
(a) In a chemical reaction, two gases combine to form a solid. What do you expect for the sign of ΔS?
Indicate whether each statement is true or false. (a) Unlike enthalpy, where we can only ever know changes in H, we can know absolute values of S. (b) If you heat a gas such as CO2, you will increase its degrees of translational, rotational and vibrational motions. (c) CO2(g) and Ar(g) have nearly the same molar mass. At a given temperature, they will have the same number of microstates.
For each of the following pairs, predict which substance possesses the larger entropy per mole: (a) 1 mol of O2(g) at 300 °C, 0.01 atm, or 1 mol of O3(g) at 300 °C, 0.01 atm