Chapter 19, Problem 4
Predict the signs of ΔH and ΔS for this reaction. Explain your choice.
Video transcript
Two different gases occupy the two bulbs shown here. Consider the process that occurs when the stopcock is opened, assuming the gases behave ideally. (d) How does the process affect the entropy of the surroundings?
b. If energy can flow in and out of the system to maintain a constant temperature during the process, what can you say about the entropy change of the surroundings as a result of this process?
The accompanying diagram shows how entropy varies with temperature for a substance that is a gas at the highest temperature shown. (c) If this substance is a perfect crystal at T = 0 K, what is the value of S at this temperature?
Isomers are molecules that have the same chemical formula but different arrangements of atoms, as shown here for two isomers of pentane, C5H12.
(a) Do you expect a significant difference in the enthalpy of combustion of the two isomers? Explain.
Isomers are molecules that have the same chemical formula but different arrangements of atoms, as shown here for two isomers of pentane, C5H12.
(b) Which isomer do you expect to have the higher standard molar entropy? Explain.